Ontology highlight
ABSTRACT:
SUBMITTER: Buckley AM
PROVIDER: S-EPMC8597163 | biostudies-literature | 2021 Oct
REPOSITORIES: biostudies-literature
ChemCatChem 20210823 20
A new class of dirhodium carboxylate catalysts have been designed and synthesized from 2-fenchyloxy or 2-menthyloxy arylacetic acids which display excellent enantioselectivity across a range of transformations of α-diazocarbonyl compounds. The catalysts were successfully applied to enantioselective C-H insertion reactions of aryldiazoacetates and α-diazo-β-oxosulfones affording the respective products in up to 93 % ee with excellent trans diastereoselectivity in most cases. Furthermore, efficien ...[more]