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Cationic dirhodium carboxylate-catalyzed synthesis of dihydropyrimidones from propargyl ureas.

ABSTRACT: Cationic Rh(II) complexes are able to catalyze the regioselective hydroamination of propargyl ureas in a 6-endo fashion. This transformation permits access to interesting substitution patterns of dihydropyrimidines which have found use as nucleotide exchange factor inhibitors.

SUBMITTER: Yang M 

PROVIDER: S-EPMC3690933 | biostudies-literature | 2013 Jul

REPOSITORIES: biostudies-literature

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Cationic dirhodium carboxylate-catalyzed synthesis of dihydropyrimidones from propargyl ureas.

Yang Miao M   Odelberg Shannon J SJ   Tong Zongzhong Z   Li Dean Y DY   Looper Ryan E RE  

Tetrahedron 20130701 27-28

Cationic Rh(II) complexes are able to catalyze the regioselective hydroamination of propargyl ureas in a 6-endo fashion. This transformation permits access to interesting substitution patterns of dihydropyrimidines which have found use as nucleotide exchange factor inhibitors. ...[more]

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