Dataset Information

Luminescent Lead Halide Ionic Liquids for High-Spatial-Resolution Fast Neutron Imaging.

ABSTRACT: The fast neutron imaging technique with recoil proton detection harbors significant potential for imaging of thick, large-scale objects containing high-Z elements. However, the challenge to find efficient fast neutron scintillators with high spatial resolution is ongoing. The list of requirements for such scintillators is long and demanding: a proton-rich, scattering-free material combining high light yield with the absence of light reabsorption. To meet these challenges, we look for a suitable material among a rising class of 0D organic-inorganic Pb(II) halide hybrids. The use of large organic cations, e.g., trihexyltetradecylphosphonium, results in room-temperature ionic liquids that combine highly Stokes-shifted (up to 1.7 eV), reabsorption-free, and efficient emission (photoluminescence quantum yield up to 60%) from molecularly small and dense (PbX₂ molar fraction up to 0.33) emitting centers. We investigate the optical properties of the resulting ionic liquids and showcase their utility as fast neutron imaging scintillators. Concomitantly with good light yield, such fast-neutron scintillators exhibit both higher spatial resolution and lower γ-ray sensitivity compared with commercial ZnS:Cu-based screens.

SUBMITTER: Morad V

PROVIDER: S-EPMC8603383 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature

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Luminescent Lead Halide Ionic Liquids for High-Spatial-Resolution Fast Neutron Imaging.

Morad Viktoriia V McCall Kyle M KM Sakhatskyi Kostiantyn K Lehmann Eberhard E Walfort Bernhard B Losko Adrian S AS Trtik Pavel P Strobl Markus M Yakunin Sergii S Kovalenko Maksym V MV

ACS photonics 20211025 11

The fast neutron imaging technique with recoil proton detection harbors significant potential for imaging of thick, large-scale objects containing high-Z elements. However, the challenge to find efficient fast neutron scintillators with high spatial resolution is ongoing. The list of requirements for such scintillators is long and demanding: a proton-rich, scattering-free material combining high light yield with the absence of light reabsorption. To meet these challenges, we look for a suitable ...[more]

PMID: 34820475

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Dataset Information

Luminescent Lead Halide Ionic Liquids for High-Spatial-Resolution Fast Neutron Imaging.

Publications

Luminescent Lead Halide Ionic Liquids for High-Spatial-Resolution Fast Neutron Imaging.

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