Browse
Submit Data
Databases
API
Help

Dataset Information

18 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bridging Hydrometallurgy and Biochemistry: A Protein-Based Process for Recovery and Separation of Rare Earth Elements.

ABSTRACT: The extraction and subsequent separation of individual rare earth elements (REEs) from REE-bearing feedstocks represent a challenging yet essential task for the growth and sustainability of renewable energy technologies. As an important step toward overcoming the technical and environmental limitations of current REE processing methods, we demonstrate a biobased, all-aqueous REE extraction and separation scheme using the REE-selective lanmodulin protein. Lanmodulin was conjugated onto porous support materials using thiol-maleimide chemistry to enable tandem REE purification and separation under flow-through conditions. Immobilized lanmodulin maintains the attractive properties of the soluble protein, including remarkable REE selectivity, the ability to bind REEs at low pH, and high stability over numerous low-pH adsorption/desorption cycles. We further demonstrate the ability of immobilized lanmodulin to achieve high-purity separation of the clean-energy-critical REE pair Nd/Dy and to transform a low-grade leachate (0.043 mol % REEs) into separate heavy and light REE fractions (88 mol % purity of total REEs) in a single column run while using ∼90% of the column capacity. This ability to achieve, for the first time, tandem extraction and grouped separation of REEs from very complex aqueous feedstock solutions without requiring organic solvents establishes this lanmodulin-based approach as an important advance for sustainable hydrometallurgy.

SUBMITTER: Dong Z

PROVIDER: S-EPMC8614107 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Functionalized ionic liquids based on vegetable oils for rare earth elements recovery.

Project description:Functionalized ionic liquids (FILs) based on vegetable oils have been directly synthesized and used for the first time to extract rare earth elements (REEs). Carbon dioxide gas is introduced to successfully strip REE-loaded FILs in the presence of water. The novel extraction process reveals some advantages of accessibility, biocompatibility and sustainability as well as cost efficiency.

| S-EPMC9055440 | biostudies-literature

The Supported Boro-Additive Effect for the Selective Recovery of Dy Elements from Rare-Earth-Elements-Based Magnets.

Project description:Liquid metal extraction (LME) for recycling rare-earth elements from magnets is studied, in the present study, to examine its suitability as an environmentally friendly alternative for a circular economy. While Nd (neodymium) extraction efficiency can easily reach almost 100%, based on the high reactivity of Mg (magnesium), Dy (dysprosium) extraction has been limited because of the Dy-Fe intermetallic phase as the main extractive bottleneck. In the present paper, the boro-additive effect is designed thermodynamically and examined in the ternary and quinary systems to improve the selectivity of recovery. Based on the strong chemical affinity between B (boron) and Fe, the effect of excess boron, which is produced by the depletion of B in FeB by Mg, successfully resulted in the formation of Fe2B instead of Dy-Fe bonding. However, the growth of the Fe2B layer, which is the reason for the isolated Mg, leads to the production of other byproducts, rare-earth borides (RB4, R = Nd and Dy), as the side effect. By adjusting the ratio of FeB, the extraction efficiency of Dy over 12 h with FeB addition is improved to 80%, which is almost the same extraction efficiency of the conventional LME process over 24 h.

| S-EPMC9101444 | biostudies-literature

Recovery of Rare Earth Elements from Wastewater Towards a Circular Economy.

Project description:The use of rare earth elements is a growing trend in diverse industrial activities, leading to the need for eco-friendly approaches to their efficient recovery and reuse. The aim of this work is the development of an environmentally friendly and competitive technology for the recovery of those elements from wastewater. Kinetic and equilibria batch assays were performed with zeolite, with and without bacterial biofilm, to entrap rare earth ions from aqueous solution. Continuous assays were also performed in column setups. Over 90% removal of lanthanum and cerium was achieved using zeolite as sorbent, with and without biofilm, decreasing to 70% and 80%, respectively, when suspended Bacillus cereus was used. Desorption from the zeolite reached over 60%, regardless of the tested conditions. When in continuous flow in columns, the removal yield was similar for all of the rare earth elements tested. Lanthanum and cerium were the elements most easily removed by all tested sorbents when tested in single- or multi-solute solutions, in batch and column assays. Rare earth removal from wastewater in open setups is possible, as well as their recovery by desorption processes, allowing a continuous mode of operation.

| S-EPMC6471397 | biostudies-literature

Rationally designed mineralization for selective recovery of the rare earth elements.

Project description:The increasing demand for rare earth (RE) elements in advanced materials for permanent magnets, rechargeable batteries, catalysts and lamp phosphors necessitates environmentally friendly approaches for their recovery and separation. Here, we propose a mineralization concept for direct extraction of RE ions with Lamp (lanthanide ion mineralization peptide). In aqueous solution containing various metal ions, Lamp promotes the generation of RE hydroxide species with which it binds to form hydrophobic complexes that accumulate spontaneously as insoluble precipitates, even under physiological conditions (pH ∼6.0). This concept for stabilization of an insoluble lanthanide hydroxide complex with an artificial peptide also works in combination with stable scaffolds like synthetic macromolecules and proteins. Our strategy opens the possibility for selective separation of target metal elements from seawater and industrial wastewater under mild conditions without additional energy input.

| S-EPMC5458567 | biostudies-literature

Rare Earth Elements Recovery and Waste Management of Municipal Solid Waste Incineration Ash

Project description: Not available

| S-EPMC10840445 | biostudies-literature

Rare earth elements from waste.

Project description:Rare earth elements (REEs) are critical materials in electronics and clean technologies. With the diminishing of easily accessible minerals for mining, the REE recovery from waste is an alternative toward a circular economy. Present methods for REE recovery suffer from lengthy purifications, low extractability, and high wastewater streams. Here, we report an ultrafast electrothermal process (~3000°C, ~1 s) based on flash Joule heating (FJH) for activating wastes to improve REE extractability. FJH thermally degrades or reduces the hard-to-dissolve REE species to components with high thermodynamic solubility, leading to ~2× increase in leachability and high recovery yields using diluted acid (e.g., 0.1 M HCl). The activation strategy is feasible for various wastes including coal fly ash, bauxite residue, and electronic waste. The rapid FJH process is energy-efficient with a low electrical energy consumption of 600 kWh ton-1. The potential for this route to be rapidly scaled is outlined.

| S-EPMC8827657 | biostudies-literature

Advancing Rare-Earth Separation by Machine Learning.

Project description:Constituting the bulk of rare-earth elements, lanthanides need to be separated to fully realize their potential as critical materials in many important technologies. The discovery of new ligands for improving rare-earth separations by solvent extraction, the most practical rare-earth separation process, is still largely based on trial and error, a low-throughput and inefficient approach. A predictive model that allows high-throughput screening of ligands is needed to identify suitable ligands to achieve enhanced separation performance. Here, we show that deep neural networks, trained on the available experimental data, can be used to predict accurate distribution coefficients for solvent extraction of lanthanide ions, thereby opening the door to high-throughput screening of ligands for rare-earth separations. One innovative approach that we employed is a combined representation of ligands with both molecular physicochemical descriptors and atomic extended-connectivity fingerprints, which greatly boosts the accuracy of the trained model. More importantly, we synthesized four new ligands and found that the predicted distribution coefficients from our trained machine-learning model match well with the measured values. Therefore, our machine-learning approach paves the way for accelerating the discovery of new ligands for rare-earth separations.

| S-EPMC9241157 | biostudies-literature

Innovative Application of Mechanical Activation for Rare Earth Elements Recovering: Process Optimization and Mechanism Exploration.

Project description:With the rapidly expanding use of fluorescent lamps (FLs) and increasing interest in conservation and sustainable utilization of critical metals such as rare earth elements (REEs), the recovering of REEs from phosphors in waste FLs is becoming a critical environmental and economic issue. To effectively recycle REEs with metallurgical methods, mechanical activation by ball milling was introduced to pretreat the waste phosphors. This current study put the emphasis on the mechanical activation and leaching processes for REEs, and explored the feasibility of the method from both theoretical and practical standpoints. Results showed physicochemical changes of structural destruction and particle size reduction after mechanical activation, leading to the easy dissolution of REEs in the activated samples. Under optimal conditions, dissolution yields of 89.4%, 93.1% and 94.6% for Tb, Eu and Y, respectively, were achieved from activated waste phosphors using hydrochloric acid as the dissolution agent. The shrinking core model proved to be the most applicable for the leaching procedure, with an apparent activation energy of 10.96 ± 2.79 kJ/mol. This novel process indicates that mechanical activation is an efficient method for recovering REEs from waste phosphors, and it has promising potential for REE recovery with low cost and high efficiency.

| S-EPMC4730208 | biostudies-literature

Direct Recovery of the Rare Earth Elements Using a Silk Displaying a Metal-Recognizing Peptide.

Project description:Rare earth elements (RE) are indispensable metallic resources in the production of advanced materials; hence, a cost- and energy-effective recovery process is required to meet the rapidly increasing RE demand. Here, we propose an artificial RE recovery approach that uses a functional silk displaying a RE-recognizing peptide. Using the piggyBac system, we constructed a transgenic silkworm in which one or two copies of the gene coding for the RE-recognizing peptide (Lamp1) was fused with that of the fibroin L (FibL) protein. The purified FibL-Lamp1 fusion protein from the transgenic silkworm was able to recognize dysprosium (Dy3+), a RE, under physiological conditions. This method can also be used with silk from which sericin has been removed. Furthermore, the Dy-recovery ability of this silk was significantly improved by crushing the silk. Our simple approach is expected to facilitate the direct recovery of RE from an actual mixed solution of metal ions, such as seawater and industrial wastewater, under mild conditions without additional energy input.

| S-EPMC7037070 | biostudies-literature

Terephthalaldehyde-Phenolic Resins as a Solid-Phase Extraction System for the Recovery of Rare-Earth Elements.

Project description:Rare-earth elements (REEs) are involved in most high technology devices and have become critical for many countries. The progress of processes for the extraction and recovery of REEs is therefore essential. Liquid-solid extraction methods are an attractive alternative to the conventional solvent extraction process used for the separation and/or purification of REEs. For this purpose, a solid-phase extraction system was investigated for the extraction and valorization of REEs. Ion-exchange resins were synthesized involving the condensation of terephthalaldehyde with resorcinol under alkaline conditions. The terephthalaldehyde, which is a non-hazardous aromatic dialdehyde, was used as an alternative to formaldehyde that is toxic and traditionally involved to prepare phenolic ion-exchange resins. The resulting formaldehyde-free resole-type phenolic resins were characterized and their ion-exchange capacity was investigated in regard to the extraction of rare-earth elements. We herein present a promising formaldehyde and phenol-free as a potential candidate for solid-liquid extraction REE with a capacity higher than 50 mg/g and the possibility to back-extract the REEs by a striping step using a 2 M HNO3 solution.

| S-EPMC8780303 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data