Dataset Information

Novel catalytic degradation of Diazinon with ozonation/mg-Al layered double hydroxides: optimization, modeling, and dispersive liquid-liquid microextraction.

ABSTRACT:

Purpose

In this study MgAl- layered double hydroxides (MgAl-LDH) nanoparticles were prepared by a simple and fast co-precipitation method and used as a catalyst in the ozonation process to degrade diazinon from aqueous solutions.

Methods

The structure of the synthesized MgAl-LDH was investigated by X-ray diffraction pattern (XRD) and field emission scanning electron microscope-energy dispersive spectroscopy (FESEM-EDX). The response surface methodology (RSM) was used to investigate the effects of different parameters including of reaction time, initial diazinon concentration, pH, and LDH dose on the removal of diazinon by MgAl-LDH catalytic ozonation process. Central Composite Design (CCD) was employed for the optimization and modeling of the process. Dispersive liquid-liquid microextraction (DLLME) method was used to extract diazinon from aqueous samples. The GC-Mass analysis was performed to determine intermediate compounds during diazinon degradation reactions. To evaluate the process performance, TOC and COD removal were measured under optimum conditions.

Results

The highest removal efficiency of 92% was observed in optimum conditions as follow; initial diazinon concentration: 120 mg/L, pH: 8.25, LDH dose: 750 mg/L, and reaction time: 70 min. The quadratic model was obtained with a good fit. The removal of COD and TOC were 80% and 74%, respectively.

Conclusion

This process can be suggested and used in the treatment of various industrial wastewaters.

Supplementary information

The online version contains supplementary material available at 10.1007/s40201-021-00687-w.

SUBMITTER: Malakootian M

PROVIDER: S-EPMC8617138 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Novel catalytic degradation of Diazinon with ozonation/mg-Al layered double hydroxides: optimization, modeling, and dispersive liquid-liquid microextraction.

Malakootian Mohammad M Shahamat Yousef Dadban YD Mahdizadeh Hakimeh H

Journal of environmental health science & engineering 20210617 2

<h4>Purpose</h4>In this study MgAl- layered double hydroxides (MgAl-LDH) nanoparticles were prepared by a simple and fast co-precipitation method and used as a catalyst in the ozonation process to degrade diazinon from aqueous solutions.<h4>Methods</h4>The structure of the synthesized MgAl-LDH was investigated by X-ray diffraction pattern (XRD) and field emission scanning electron microscope-energy dispersive spectroscopy (FESEM-EDX). The response surface methodology (RSM) was used to investigat ...[more]

PMID: 34900267

Similar Datasets

Project description:Layered double hydroxides (LDHs) are an ideal platform to host catalytic metal centers for water oxidation (WO) owing to the high accessibility of water to the interlayer region, which makes all centers potentially reachable and activated. Herein, we report the syntheses of three iridium-doped zinc-aluminum LDHs (Ir-LDHs) nanomaterials (1-3, with about 80 nm of planar size and a thickness of 8 nm as derived by field emission scanning electron microscopy and powder X-ray diffraction studies, respectively), carried out in the confined aqueous environment of reverse micelles, through a very simple and versatile procedure. These materials exhibit excellent catalytic performances in WO driven by NaIO4 at neutral pH and 25 °C, with an iridium content as low as 0.5 mol % (∼0.8 wt %), leading to quantitative oxygen yields (based on utilized NaIO4, turnover number up to ∼10,000). Nanomaterials 1-3 display the highest ever reported turnover frequency values (up to 402 min-1) for any heterogeneous and heterogenized catalyst, comparable only to those of the most efficient molecular iridium catalysts, tested under similar reaction conditions. The boost in activity can be traced to the increased surface area and pore volume (>5 times and 1 order of magnitude, respectively, higher than those of micrometric materials of size 0.3-1 μm) estimated for the nanosized particles, which guarantee higher noble metal accessibility. X-ray absorption spectroscopy (XAS) studies suggest that 1-3 nanomaterials, as-prepared and after catalysis, contain a mixture of isolated, single octahedral Ir(III) sites, with no evidence of Ir-Ir scattering from second-nearest neighbors, excluding the presence of IrO2 nanoparticles. The combination of the results obtained from XAS, elemental analysis, and ionic chromatography strongly suggests that iridium is embedded in the brucite-like structure of LDHs, having four hydroxyls and two chlorides as first neighbors. These results demonstrate that nanometric LDHs can be successfully exploited to engineer efficient WOCs, minimizing the amount of iridium used, consistent with the principle of the noble-metal atom economy.

Dataset Information

Novel catalytic degradation of Diazinon with ozonation/mg-Al layered double hydroxides: optimization, modeling, and dispersive liquid-liquid microextraction.

Purpose

Methods

Results

Conclusion

Supplementary information

Publications

Novel catalytic degradation of Diazinon with ozonation/mg-Al layered double hydroxides: optimization, modeling, and dispersive liquid-liquid microextraction.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets