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Application of Amberlite IRA 402 Resin Adsorption and Laccase Treatment for Acid Blue 113 Removal from Aqueous Media.

ABSTRACT: Despite Acid Blue 113 (AB 113)'s extensive use and negative environmental impact, very few studies have focused on its efficient and environmentally friendly removal. This research aims the removal of AB 113 from environmental aqueous media and its consequent enzymatic biodegradation. A strongly basic anion exchange resin in Cl^- form, Amberlite IRA 402 (IRA 402(Cl^-)) was used for AB 113 adsorption and a laccase was used to further biodegrade it. For the first time, two novel, efficient and environmentally friendly physical-chemical and biological assays for AB 113 wastewater removal and subsequent biodegradation were combined. The adsorption of AB 113 onto IRA 402(Cl^-) was tested in batch and continuous flux modes. Influence of contact time, concentration and desorption in acidic media were evaluated. The kinetic data were best modulated by the Lagergren model with R² = 0.9275. The Langmuir isotherm model best fitted the experimental data, and the maximum adsorption capacity was 130 mg/g. Dye, resin and AB113 loaded resin were characterized by thermogravimetry and FTIR to evaluate their physical chemical properties modification. Based on the performed studies, a consecutive methodology is proposed, incorporating the ion exchange process in the first stage and the biodegradation process in the second. Thus, in the second stage the residual concentration of AB 113 is reduced by an efficient bio-degradation process produced by the laccase at pH = 4.

SUBMITTER: Marin NM

PROVIDER: S-EPMC8621439 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:Platinum is a precious metal with many applications, such as: catalytic converters, laboratory equipment, electrical contacts and electrodes, digital thermometers, dentistry, and jewellery. Due to its broad usage, it is essential to recover it from waste solutions resulted out of different technological processes in which it is used. Over the years, several recovery techniques were developed, adsorption being one of the simplest, effective and economical method used for platinum recovery. In the present paper a new adsorbent material (XAD7-DB30C10) for Pt (IV) recovery was used. Produced adsorbent material was characterized by X-ray dispersion (EDX), scanning electron microscopy (SEM) analysis, Fourier Transform Infrared Spectroscopy and Brunauer-Emmett-Teller (BET) surface area analysis. Adsorption isotherms, kinetic models, thermodynamic parameters and adsorption mechanism are presented in this paper. Experimental data were fitted using three non-linear adsorption isotherms: Langmuir, Freundlich and Sips, being better fitted by Sips adsorption isotherm. Obtained kinetic data were correlated well with the pseudo-second-order kinetic model, indicating that the chemical sorption was the rate-limiting step. Thermodynamic parameters (?G°, ?H°, ?S°) showed that the adsorption process was endothermic and spontaneous. After adsorption, metallic platinum was recovered from the exhausted adsorbent material by thermal treatment. Adsorption process optimisation by design of experiments was also performed, using as input obtained experimental data, and taking into account that initial platinum concentration and contact time have a significant effect on the adsorption capacity. From the optimisation process, it has been found that the maximum adsorption capacity is obtained at the maximum variation domains of the factors. By optimizing the process, a maximum adsorption capacity of 15.03 mg g-1 was achieved at a contact time of 190 min, initial concentration of 141.06 mg L-1 and the temperature of 45 °C.

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Application of Amberlite IRA 402 Resin Adsorption and Laccase Treatment for Acid Blue 113 Removal from Aqueous Media.

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