Dataset Information

Performance and Mechanisms of PropS-SH/HA Coatings in the Inhibition of Pyrite Oxidation.

ABSTRACT: Acid mine drainage (AMD) entering the environment will cause long-term environmental pollution and ecological damage, the treatment or remediation for which has become a difficult worldwide problem. To control AMD at the source, a novel composite coating, hydroxyapatite (HA) as the filler embedded in a γ-mercaptopropyltrimethoxysilane (PropS-SH) coating, was introduced in this study. The performance and mechanisms of PropS-SH/HA coatings in the inhibition of pyrite oxidation were investigated by chemical leaching testing and material structure characterization. The results of the investigations revealed that the addition of an appropriate amount of HA can enhance the passivation efficiency of the PropS-SH coating. The best coating was obtained from 3% (v/v) of PropS-SH solution with 16 wt % HA, as this coating decreased pyrite oxidation by 78.7% (based on total Fe release). The main mechanism of PropS-SH/HA for the inhibition of pyrite oxidation involved the generation of a PropS-SH network through a polycondensation reaction. The addition of HA increased the stability of the passivation film composed of PropS-SH as well as the combining capacity of PropS-SH/HA through the formation of Si-O-Si and Fe-O-Si bonds, respectively.

SUBMITTER: Yang S

PROVIDER: S-EPMC8637958 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature

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Performance and Mechanisms of PropS-SH/HA Coatings in the Inhibition of Pyrite Oxidation.

Yang Shuang S Luo Tianlie T Fan Jiajun J Zhou Chengzhi C Hu Mengyao M Wang Jinyu J Wen Lijia L Qin Li L Liu Guo G

ACS omega 20211118 47

Acid mine drainage (AMD) entering the environment will cause long-term environmental pollution and ecological damage, the treatment or remediation for which has become a difficult worldwide problem. To control AMD at the source, a novel composite coating, hydroxyapatite (HA) as the filler embedded in a γ-mercaptopropyltrimethoxysilane (PropS-SH) coating, was introduced in this study. The performance and mechanisms of PropS-SH/HA coatings in the inhibition of pyrite oxidation were investigated by ...[more]

PMID: 34870024

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Project description:Pyrite (FeS2) has a very low solubility and therefore has historically been considered a sink for iron (Fe) and sulfur (S) and unavailable to biology in the absence of oxygen and oxidative weathering. Anaerobic methanogens were recently shown to reduce FeS2 and assimilate Fe and S reduction products to meet nutrient demands. However, the mechanism of FeS2 mineral reduction and the forms of Fe and S assimilated by methanogens remained unclear. Thermodynamic calculations described herein indicate that H2 at aqueous concentrations as low as 10-10 M favors the reduction of FeS2, with sulfide (HS-) and pyrrhotite (Fe1- x S) as products; abiotic laboratory experiments confirmed the reduction of FeS2 with dissolved H2 concentrations greater than 1.98 × 10-4 M H2. Growth studies of Methanosarcina barkeri provided with FeS2 as the sole source of Fe and S resulted in H2 production but at concentrations too low to drive abiotic FeS2 reduction, based on abiotic laboratory experimental data. A strain of M. barkeri with deletions in all [NiFe]-hydrogenases maintained the ability to reduce FeS2 during growth, providing further evidence that extracellular electron transport (EET) to FeS2 does not involve H2 or [NiFe]-hydrogenases. Physical contact between cells and FeS2 was required for mineral reduction but was not required to obtain Fe and S from dissolution products. The addition of a synthetic electron shuttle, anthraquinone-2,6-disulfonate, allowed for biological reduction of FeS2 when physical contact between cells and FeS2 was prohibited, indicating that exogenous electron shuttles can mediate FeS2 reduction. Transcriptomics experiments revealed upregulation of several cytoplasmic oxidoreductases during growth of M. barkeri on FeS2, which may indicate involvement in provisioning low potential electrons for EET to FeS2. Collectively, the data presented herein indicate that reduction of insoluble FeS2 by M. barkeri occurred via electron transfer from the cell surface to the mineral surface resulting in the generation of soluble HS- and mineral-associated Fe1- x S. Solubilized Fe(II), but not HS-, from mineral-associated Fe1- x S reacts with aqueous HS- yielding aqueous iron sulfur clusters (FeS aq ) that likely serve as the Fe and S source for methanogen growth and activity. FeS aq nucleation and subsequent precipitation on the surface of cells may result in accelerated EET to FeS2, resulting in positive feedback between cell activity and FeS2 reduction.

Project description:Ammoniacal thiosulfate has been used lately as an alternative lixiviant for leaching gold from sulfides ores which are not amenable for cyanidation. However, the oxidation of the sulfide minerals generates products that inhibit the dissolution of gold and can promote the degradation of the leaching solution. The complexity of the ammoniacal thiosulfate leaching system has prevented the unification and clarification of the mechanisms of oxidation of sulfide ores used for gold extraction. In this study, a method combining polarization curves, Electrochemical impedance spectroscopy (EIS), and in situ Raman spectroscopy was implemented to investigate the oxidation process of high-purity pyrite. Pyrite samples were dispersed in carbon paste electrode (CPE-Py). The polarization curves of CPE-Py exhibited an increase in current values for overpotentials greater than 0.1 V, indicating the initiation of mineral oxidation processes. Subsequently, a maximum current was observed initially, followed by subsequent decrease, indicating the occurrence of passivation processes on the electrode surface. Hydrodynamic polarization curves demonstrated that the overpotential at which the passivation process occurs is independent of mass transport, suggesting that the passivation products were formed through solid-state transformation. Impedance spectra revealed that at overpotentials below 0.1 V, a partially resolved capacitive semicircle was observed, which was associated with the resistance encountered when charge was transferred between the solution and the surface layer interface. This resistance decreased as the polarization overpotential increased, implying a decrease in charge transfer kinetics. At higher overpotentials (0.3 V-0.4 V), a second capacitive semicircle appeared, linked to the oxidation of one or several species present in the mineral. In situ Raman spectroscopy was utilized to identify the oxidation species of pyrite in ammonia-thiosulfate ((NH4)2S2O3) leaching solution at a pH = 10.2. The composition of the species varied depending on the applied anodic potential. At low anodic potentials (0.1 V), Fe(OH)2 and thiosulfate (S2O32-) were formed, while at high anodic potentials (0.4 V), iron products such as Fe3O4 and γ-FeOOH, as well as sulfide species including thiosulfate, tetrathionates and sulfates (S2O32-, S4O6-2 and SO42-) were formed.

Dataset Information

Performance and Mechanisms of PropS-SH/HA Coatings in the Inhibition of Pyrite Oxidation.

Publications

Performance and Mechanisms of PropS-SH/HA Coatings in the Inhibition of Pyrite Oxidation.

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