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Stereodivergent Access to Trisubstituted Alkenylboronate Esters through Alkene Isomerization.

ABSTRACT: We report an efficient method for the preparation of synthetically valuable trisubstituted alkenylboronate esters through alkene isomerization of their readily available 1,1-disubstituted regioisomeric counterparts. Either stereoisomer of the target alkenylboronate motif can be obtained at will from the same starting material by employing different isomerization catalysts.

SUBMITTER: Segura L 

PROVIDER: S-EPMC8650100 | biostudies-literature |

REPOSITORIES: biostudies-literature

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