Stereodivergent Access to Trisubstituted Alkenylboronate Esters through Alkene Isomerization.
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ABSTRACT: We report an efficient method for the preparation of synthetically valuable trisubstituted alkenylboronate esters through alkene isomerization of their readily available 1,1-disubstituted regioisomeric counterparts. Either stereoisomer of the target alkenylboronate motif can be obtained at will from the same starting material by employing different isomerization catalysts.
SUBMITTER: Segura L
PROVIDER: S-EPMC8650100 | biostudies-literature |
REPOSITORIES: biostudies-literature
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