Ordered Oxygen Vacancies in the Lithium-Rich Oxide Li₄CuSbO_5.5, a Triclinic Structure Type Derived from the Cubic Rocksalt Structure.

ABSTRACT: Li-rich rocksalt oxides are promising candidates as high-energy density cathode materials for next-generation Li-ion batteries because they present extremely diverse structures and compositions. Most reported materials in this family contain as many cations as anions, a characteristic of the ideal cubic closed-packed rocksalt composition. In this work, a new rocksalt-derived structure type is stabilized by selecting divalent Cu and pentavalent Sb cations to favor the formation of oxygen vacancies during synthesis. The structure and composition of the oxygen-deficient Li₄CuSbO_5.5□_0.5 phase is characterized by combining X-ray and neutron diffraction, ICP-OES, XAS, and magnetometry measurements. The ordering of cations and oxygen vacancies is discussed in comparison with the related Li₂CuO₂□₁ and Li₅SbO₅□₁ phases. The electrochemical properties of this material are presented, with only 0.55 Li⁺ extracted upon oxidation, corresponding to a limited utilization of cationic and/or anionic redox, whereas more than 2 Li⁺ ions can be reversibly inserted upon reduction to 1 V vs Li⁺/Li, a large capacity attributed to a conversion reaction and the reduction of Cu²⁺ to Cu⁰. Control of the formation of oxygen vacancies in Li-rich rocksalt oxides by selecting appropriate cations and synthesis conditions affords a new route for tuning the electrochemical properties of cathode materials for Li-ion batteries. Furthermore, the development of material models of the required level of detail to predict phase diagrams and electrochemical properties, including oxygen release in Li-rich rocksalt oxides, still relies on the accurate prediction of crystal structures. Experimental identification of new accessible structure types stabilized by oxygen vacancies represents a valuable step forward in the development of predictive models.

SUBMITTER: Perez AJ 

PROVIDER: S-EPMC8693191 | biostudies-literature |

REPOSITORIES: biostudies-literature