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Characterisation of hydration water in Nafion membrane.


ABSTRACT: Nafion, a polytetrafluoroethylene polymer with perfluorinated-vinyl-polyether side chains ending in sulfonic acid groups, is widely used as the proton-exchange membrane in polymer electrolyte fuel cells, particularly low temperature hydrogen-oxygen fuel cells. The state of hydration of the sulfonic acid groups is crucial to its operation. By using a combination of inelastic neutron scattering (INS) and infrared spectroscopies, and by comparison to a series of trifluoromethanesulfonic acid hydrates of well-defined stoichiometry, we characterise how the hydration changes as a function of water content.

SUBMITTER: Parker SF 

PROVIDER: S-EPMC8695510 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature

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Characterisation of hydration water in Nafion membrane.

Parker Stewart F SF   Shah Shrey S  

RSC advances 20210301 16


Nafion, a polytetrafluoroethylene polymer with perfluorinated-vinyl-polyether side chains ending in sulfonic acid groups, is widely used as the proton-exchange membrane in polymer electrolyte fuel cells, particularly low temperature hydrogen-oxygen fuel cells. The state of hydration of the sulfonic acid groups is crucial to its operation. By using a combination of inelastic neutron scattering (INS) and infrared spectroscopies, and by comparison to a series of trifluoromethanesulfonic acid hydrat  ...[more]

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