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Improved Thermo-Mechanical Properties and Reduced Hydrogen Permeation of Short Side-Chain Perfluorosulfonic Acid Membranes Doped with Ti₃C₂T_x.

ABSTRACT: Benefiting from its large specific surface with functional -OH/-F groups, Ti₃C₂T_x, a typical two-dimensional (2D) material in the recently developed MXene family, was synthesized and used as a filler to improve the properties of the short side-chain (SSC) perfluorosulfonic acid (PFSA) proton exchange membrane. It is found that the proton conductivity is enhanced by 15% while the hydrogen permeation is reduced by 45% after the addition of 1.5 wt% Ti₃C₂T_x filler into the SSC PFSA membrane. The improved proton conductivity of the composite membrane could be associated with the improved proton transport environment in the presence of the hydrophilic functional groups (such as -OH) of the Ti₃C₂T_x filler. The significantly reduced hydrogen permeation could be attributed to the incorporation of the impermeable Ti₃C₂T_x 2D fillers and the decreased hydrophilic ionic domain spacing examined by the small angle X-ray scattering (SAXS) for the composite membrane. Furthermore, improved thermo-mechanical properties of the SSC/Ti₃C₂T_x composite membrane were measured by dynamic mechanical analyzer (DMA) and tensile strength testing. The demonstrated higher proton conductivity, lower hydrogen permeation, and improved thermo-mechanical stability indicate that the SSC/Ti₃C₂T_x composite membranes could be a potential membrane material for PEM fuel cells operating above the water boiling temperature.

SUBMITTER: Guan P

PROVIDER: S-EPMC8703456 | biostudies-literature |

REPOSITORIES: biostudies-literature

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