One-Step Solution Deposition of Antimony Selenoiodide Films via Precursor Engineering for Lead-Free Solar Cell Applications.
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ABSTRACT: Ternary chalcohalides are promising lead-free photovoltaic materials with excellent optoelectronic properties. We propose a simple one-step solution-phase precursor-engineering method for antimony selenoiodide (SbSeI) film fabrication. SbSeI films were fabricated by spin-coating the precursor solution, and heating. Various precursor solutions were synthesized by adjusting the molar ratio of two solutions based on SbCl3-selenourea and SbI3. The results suggest that both the molar ratio and the heating temperature play key roles in film phase and morphology. Nanostructured SbSeI films with a high crystallinity were obtained at a molar ratio of 1:1.5 and a temperature of 150 °C. The proposed method could be also used to fabricate (Bi,Sb)SeI.
SUBMITTER: Choi YC
PROVIDER: S-EPMC8703622 | biostudies-literature |
REPOSITORIES: biostudies-literature
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