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Self-Assembly of [3]Catenane and [4]Catenane Based on Neutral Organometallic Scaffolds.


ABSTRACT: Transition metal-mediated templating and self-assembly have shown great potential to construct mechanically interlocked molecules. Herein, we describe the formation of the bimetallic [3]catenane and [4]catenane based on neutral organometallic scaffolds via the orthogonality of platinum-to-oxygen coordination-driven self-assembly and copper(I) template-directed strategy of a [2]pseudorotaxane. The structures of these bimetallic [3]catenane and [4]catenane were characterized by multinuclear NMR {1H and 31P} spectroscopy, electrospray ionization time-of-flight mass spectrometry (ESI-TOF-MS), and PM6 semiempirical molecular orbital theoretical calculations. In addition, single-crystal X-ray analyses of the [3]catenane revealed two asymmetric [2]pseudorotaxane units inside the metallacycle. It was discovered that tubular structures were formed through the stacking of individual [3]catenane molecules driven by the strong π-π interactions.

SUBMITTER: Wu GY 

PROVIDER: S-EPMC8710481 | biostudies-literature | 2021

REPOSITORIES: biostudies-literature

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Self-Assembly of [3]Catenane and [4]Catenane Based on Neutral Organometallic Scaffolds.

Wu Gui-Yuan GY   Zhu Hong-Juan HJ   Pan Fang-Fang FF   Sheng Xiao-Wei XW   Zhang Ming-Rui MR   Zhang Xianyi X   Yao Guangxin G   Qu Hang H   Lu Zhou Z  

Frontiers in chemistry 20211213


Transition metal-mediated templating and self-assembly have shown great potential to construct mechanically interlocked molecules. Herein, we describe the formation of the bimetallic [3]catenane and [4]catenane based on neutral organometallic scaffolds <i>via</i> the orthogonality of platinum-to-oxygen coordination-driven self-assembly and copper(I) template-directed strategy of a [2]pseudorotaxane. The structures of these bimetallic [3]catenane and [4]catenane were characterized by multinuclear  ...[more]

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