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Opportunities and challenges of applying advanced X-ray spectroscopy to actinide and lanthanide N-donor ligand systems.

ABSTRACT: N-donor ligands such as n-Pr-BTP [2,6-bis(5,6-dipropyl-1,2,4-triazin-3-yl)pyridine] preferentially bind trivalent actinides (An³⁺) over trivalent lanthanides (Ln³⁺) in liquid-liquid separation. However, the chemical and physical processes responsible for this selectivity are not yet well understood. Here, an explorative comparative X-ray spectroscopy and computational (L₃-edge) study for the An/Ln L₃-edge and the N K-edge of [An/Ln(n-Pr-BTP)₃](NO₃)₃, [Ln(n-Pr-BTP)₃](CF₃SO₃)₃ and [Ln(n-Pr-BTP)₃](ClO₄)₃ complexes is presented. High-resolution X-ray absorption near-edge structure (HR-XANES) L₃-edge data reveal additional features in the pre- and post-edge range of the spectra that are investigated using the quantum chemical codes FEFF and FDMNES. X-ray Raman spectroscopy studies demonstrate the applicability of this novel technique for investigations of liquid samples of partitioning systems at the N K-edge.

SUBMITTER: Pruessmann T

PROVIDER: S-EPMC8733980 | biostudies-literature |

REPOSITORIES: biostudies-literature

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