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Crystal structure of N,N,N',N'-tetra-methyl-ethane-di-amine.

ABSTRACT: The title compound N,N,N',N'-tetra-methyl-ethanedi-amine, C₆H₁₆N₂, is a bidentate amine ligand commonly used in organolithium chemistry for deaggregation. Crystals were grown at 243 K from n-pentane solution. The complete mol-ecule is generated by a crystallographic center of symmetry and the conformation of the di-amine is anti-periplanar. To investigate the inter-molecular inter-actions, a Hirshfeld surface analysis was performed. It showed that H⋯H (van der Waals) inter-actions dominate with a contact percentage of 92.3%.

SUBMITTER: Schrimpf T

PROVIDER: S-EPMC8739202 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature

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Crystal structure of N,N,N',N'-tetra-methyl-ethane-di-amine.

Schrimpf Tobias T Otte Felix F Strohmann Carsten C

Acta crystallographica. Section E, Crystallographic communications 20220101 Pt 1

The title compound N,N,N',N'-tetra-methyl-ethanedi-amine, C6H16N2, is a bidentate amine ligand commonly used in organolithium chemistry for deaggregation. Crystals were grown at 243 K from n-pentane solution. The complete mol-ecule is generated by a crystallographic center of symmetry and the conformation of the di-amine is anti-periplanar. To investigate the inter-molecular inter-actions, a Hirshfeld surface analysis was perfor ...[more]

PMID: 35079420

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