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Hybrid organic-inorganic crystal structure of 4-(di-methyl-amino)-pyridinium di-methyl-ammonium tetra-chlorido-lead(II).

ABSTRACT: The title compound, (C2H8N)(C7H11N2)[PbCl4], is a hybrid organic-inorganic material. It crystallizes in the space group C2/c and contains one half of a mol-ecule of lead chloride, 4-(di-methyl-amino)-pyridinium, and di-methyl-ammonium in the asymmetric unit. The crystal structure exhibits chains of lead chloride capped by 4-(di-methyl-amino)-pyridinium and di-methyl-ammoium by hydrogen bonding. This creates a one-dimensional zipper-like structure down the a axis. The crystal structure is examined and compared to a similar structure containing lead chloride and di-methyl-benzene-1,4-diaminium.

SUBMITTER: Benson CA

PROVIDER: S-EPMC5683487 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature

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Hybrid organic-inorganic crystal structure of 4-(di-methyl-amino)-pyridinium di-methyl-ammonium tetra-chlorido-lead(II).

Benson Cassidy A CA Bateman Gage G Cox Jordan M JM Benedict Jason B JB

Acta crystallographica. Section E, Crystallographic communications 20171020 Pt 11

The title compound, (C2H8N)(C7H11N2)[PbCl4], is a hybrid organic-inorganic material. It crystallizes in the space group C2/c and contains one half of a mol-ecule of lead chloride, 4-(di-methyl-amino)-pyridinium, and di-methyl-ammonium in the asymmetric unit. The crystal structure exhibits chains of lead chloride capped by 4-(di-methyl-amino)-pyridinium and di-methyl-ammoium by hydrogen bonding. This creates a one-dim ...[more]

PMID: 29152347

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