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A Water-Stable 2-Fold Interpenetrating cds Net as a Bifunctional Fluorescence-Responsive Sensor for Selective Detection of Cr(III) and Cr(VI) Ions.

ABSTRACT: Reactions of ZnSO₄∙7H₂O, N-(pyridin-3-ylmethyl)-4-(pyridin-4-yl)-1,8-naphthalimide (NI-mbpy-34), and 5-bromobenzene-1,3-dicarboxylic acid (Br-1,3-H₂bdc) afforded a luminescent coordination polymer, [Zn(Br-1,3-bdc)(NI-mbpy-34)]_n (1), under hydro(solvo)thermal conditions. Single-crystal X-ray structure analysis revealed that 1 features a three-dimensional (3-D) 2-fold interpenetrating cds (or CdSO₄) net topology with the point symbol of (6⁵·8), where the Zn(II) centers are considered as 4-connected square-planar nodes. X-ray powder diffraction (XRPD) patterns and thermogravimetric (TG) analysis confirmed that 1 shows high chemical and thermal stabilities. Notably, 1 displayed solvent dependent photoluminescence properties; the fluorescence intensity and emission maximum of 1 in different solvent suspensions varied when a solvent was changed. Furthermore, the H₂O suspension of 1 exhibited blue fluorescence emission and thus can be treated as a selective and sensitive fluorescent probe for turn-on detection of Cr³⁺ cations through absorbance caused enhancement (ACE) mechanism and turn-off detection of Cr₂O₇^2-/CrO₄^2- anions through collaboration of the absorption competition and energy transfer process, with limit of detection (LOD) as low as μM scale.

SUBMITTER: Tsai MJ

PROVIDER: S-EPMC8746465 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:Heavy metal ions in water refer to significant risks to the biological system due to their high toxicity. Therefore, the decontamination of water polluted by heavy metal ions attracts significant interest of researchers. Adsorption by nanomaterials has been a widely used technique for removing heavy metal ions from water. Chitosan was extracted from shrimp shellfish and mixed with laboratory-prepared AgNPs/GO in the ratio of 3 : 1. A series of tests evaluates the best condition of pH, amount of adsorbent, retention time, stirring speed, temp, and initial concentration. The research was conducted under various conditions. Langmuir, Freundlich, Tempkin, and Dubinin-Radushkevich isotherms were also tested. Also, the column adsorption experiment was carried out on industrial wastewater at different flow rates and column bed heights. The optimal values of the contact time, pH, and adsorbent dose of Cr(vi) were found to be 80 min, 4, and 0.1 g 100 mL-1, respectively, at room temperature (30 °C), agitation at 150 rpm, and initial concentration of 50 ppm. On the other hand, the optimal value of contact time, pH, and adsorbent dose of Fe(iii) were found to be 30 min, 6, and 0.02 g 100 mL-1, respectively, at room temp (30 °C) with a stirring speed of 250 rpm and an initial concentration of 40 ppm. For Cr(vi) and Fe(iii), equilibrium studies show that the data fit the Freundlich isotherm well (correlation coefficient, R 2 = 0.98) (III). A link between the pseudo-second order active model and data fitting the pseudo-first order active models were made. Within the intraparticle diffusion model, there are four stages that the mechanism must go through before it is at equilibrium. The adsorbent was tested in an industrial adsorbent column. This test proves that the nanocomposite's adsorption capacity can be restored by washing it with 0.1 M HCl, as shown by the periodicity test. After four cycles, the amount of Cr(vi) adsorbed on AgNPs/GO/chitosan was just 20%, which is insufficient for further adsorption experiments. Cr(vi) removal rates (%R) decreased slightly.

Dataset Information

A Water-Stable 2-Fold Interpenetrating cds Net as a Bifunctional Fluorescence-Responsive Sensor for Selective Detection of Cr(III) and Cr(VI) Ions.

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