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Versatile Strategy for the Preparation of Woody Biochar with Oxygen-Rich Groups and Enhanced Porosity for Highly Efficient Cr(VI) Removal.

ABSTRACT: Biochar is widely used to remove hexavalent chromium [Cr(VI)] from wastewater through adsorption, which is recognized as a facile, cost-efficient, and high-selectivity approach. In this study, a versatile strategy that combines delignification with subsequent carbonization and KOH activation is proposed to prepare a novel woody biochar from waste poplar sawdust. By virtue of the unique multilayered and honeycomb porous structure induced by delignification and activation processes, the resultant activated carbonized delignified wood (ACDW) exhibits a high specific surface area of 970.52 m² g^-1 with increasing meso- and micropores and abundant oxygen-containing functional groups. As a benign adsorbent for the uptake of Cr(VI) in wastewater, ACDW delivers a remarkable adsorption capacity of 294.86 mg g^-1 in maximum, which is significantly superior to that of unmodified counterparts and other reported biochars. Besides, the adsorption behaviors fit better with the Langmuir isotherm, the pseudo-second-order kinetic model, and the adsorption diffusion model in batch experiments. Based on the results, we put forward the conceivable adsorption mechanism that the synergistic contributions of the capillary force, electrostatic attraction, chemical complexation, and reduction action facilitate the Cr(VI) capture by ACDW.

SUBMITTER: Dong H

PROVIDER: S-EPMC8756790 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Biochar Decreases Cr Toxicity and Accumulation in Sunflower Grown in Cr(VI)-Polluted Soil.

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Project description:In this study, different types of magnetic biochar nanocomposites were synthesized using the co-precipitation method. Two biochar materials, namely, sewage sludge biochar and woodchips biochar, were prepared at two different temperatures, viz., 450 and 700 °C. These biochars were further modified with magnetic nanoparticles (Fe3O4). The modified biochar nanocomposites were characterized using field emission-scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET), SQUID analysis, X-ray photoelectron spectroscopy (XPS), and Fourier-transform infrared spectroscopy (FTIR). The potential of prepared adsorbents was examined for the removal of hexavalent chromium (Cr(VI)) and Acid orange 7 (AO7) dye from water as a function of various parameters, namely, contact time, pH of solution, amount of adsorbents, and initial concentrations of adsorbates. Various kinetic and isotherm models were tested to discuss and interpret the adsorption mechanisms. The maximum adsorption capacities of modified biochars were found as 80.96 and 110.27 mg g-1 for Cr(VI) and AO7, respectively. Magnetic biochars showed high pollutant removal efficiency after 5 cycles of adsorption/desorption. The results of this study revealed that the prepared adsorbents can be successfully used for multiple cycles to remove Cr(VI) and AO7 from water. Graphical Abstract.

| S-EPMC7417418 | biostudies-literature

Coupling of kenaf Biochar and Magnetic BiFeO3 onto Cross-linked Chitosan for Enhancing Separation Performance and Cr(VI) Ions Removal Efficiency.

Project description:Cr(VI) contamination has posed great threat to both the ecosystem and human health for its carcinogenic and mutagenic nature. A highly effective adsorbent for the removal of Cr(VI) was prepared and its adsorption mechanism was thoroughly discussed in this study. In detail, magnetic BiFeO3 and kenaf biochar were loaded on cross-linked chitosan to obtain chitosan-kenaf biochar@BiFeO3 (CKB) for improving adsorption capacity towards Cr(VI). The adsorption process of Cr(VI) onto CKB was evaluated as a function of the pH, the existence of competing ions, the initial concentration of Cr(VI) and contact time. The results show that CKB exhibits the highest adsorption capacity under the optimal pH 2.0. The presence of competing ions such as Ca2+, NO3-, SO42-, and Cl- decreases the adsorption capacity; among them, Ca2+ and NO3- show the greatest hindrance. By studying the effect of initial Cr(VI) concentration on the adsorption capacity, it was found that CKB in the solution was enough to remove Cr(VI) for all treatments (10-200 mg/L). The adsorption experimental data were well fitted with pseudo-first-order model, suggesting that chemisorption is not the dominant rate-limiting step. Freundlich isotherm model can better explain the adsorption process, indicating a non-ideal adsorption towards Cr(VI) on a heterogeneous surface of CKB. A 25-1 Fractional Factorial Design (FFD) showed that pH and initial concentration of Cr(VI) have significant influence on Cr(VI) adsorption in our reaction system. In general, excellent adsorption efficiency of CKB indicates that it may be a good candidate for the remediation of Cr(VI)-contaminating wastewater.

| S-EPMC7037466 | biostudies-literature

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