Browse
Submit Data
Databases
API
Help

Dataset Information

19 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Tuning the Sensitivity and Dynamic Range of Optical Oxygen Sensing Films by Blending Various Polymer Matrices.

ABSTRACT: In this work, eight different types of optical oxygen sensing films were prepared by impregnating indicator and matrix solution on the surface of a polypropylene microporous filter membrane. The polymer matrix of the sensing films was ethyl cellulose (EC), polymethyl methacrylate (PMMA), and their blends with different mixing ratios. Scanning electron microscopy (SEM), laser confocal microscopy, and fluorescence spectrometer were used to investigate the morphologies and optical properties of the sensing films. Phase delay measurements under different oxygen partial pressures (P_O₂) and temperatures were applied to investigate the analytical performances of the sensing film for gaseous O₂ monitoring. Results show that the response time of all the sensing films was extremely fast. The sensitivities and dynamic ranges of the sensing films with the blended polymer matrix were separately decreased and increased as the EC/PMMA ratio decreased, and the S-V curve of the sensing films blended with equal content of EC and PMMA exhibited good linearity under different temperatures, showing a promising prospect in practical application.

SUBMITTER: Zhang K

PROVIDER: S-EPMC8773664 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Tuning the dynamic range and sensitivity of optical oxygen-sensors by employing differently substituted polystyrene-derivatives.

Project description:Ten different polystyrene-derivatives were tested with respect to their potential use as matrix materials for optical oxygen sensors in combination with the platinum(II) meso-tetra(4-fluorophenyl)tetrabenzoporphyrin as indicator dye. Either halogen atoms or bulky residues were introduced as substituents on the phenyl ring. A fine-tuning of the sensor sensitivity was achieved, without compromising solubility of the indicator in the matrix by providing a chemical environment very similar to polystyrene (PS), a standard matrix in optical oxygen sensors. To put the results into perspective, the studied materials were compared to PS regarding sensitivity of the sensor, molecular weight and glass-transition temperature. The materials promise to be viable alternatives to PS with respect to the requirements posed in various sensor application fields. Some of the polymers (e.g. poly(2,6-dichlorostyrene)) promise to be of use in applications requiring measurements from 0 to 100% oxygen due to linearity across this range. Poly(4-tert-butylstyrene) and poly(2,6-fluorostyrene), on the other hand, yield sensors with increased sensitivity. Sensor stability was evaluated as a function of the matrix, a topic which has not received a lot of interest so far.

| S-EPMC3617881 | biostudies-literature

Tuning the Relaxation of Nanopatterned Polymer Films with Polymer-Grafted Nanoparticles: Observation of Entropy-Enthalpy Compensation.

Project description:Polymer films provide a versatile platform in which complex functional relief patterns can be thermally imprinted with a resolution down to few nanometers. However, a practical limitation of this method is the tendency for the imprinted patterns to relax ("slump"), leading to loss of pattern fidelity over time. While increasing temperature above glass transition temperature ( Tg) accelerates the slumping kinetics of neat films, we find that the addition of polymer-grafted nanoparticles (PGNP) can greatly enhance the thermal stability of these patterns. Specifically, increasing the concentration of poly(methyl methacrylate) (PMMA) grafted titanium dioxide (TiO2) nanoparticles in the composite films slows down film relaxation dynamics, leading to enhanced pattern stability for the temperature range that we investigated. Interestingly, slumping relaxation time is found to obey an entropy-enthalpy compensation (EEC) relationship with varying PGNP concentration, similar to recently observed relaxation of strain-induced wrinkling in glassy polymer films having variable film thickness. The compensation temperature, Tcomp was found to be in the vicintity of the bulk Tg of PMMA. Our results suggest a common origin of EEC relaxation in patterned polymer thin films and nanocomposites.

| S-EPMC6537094 | biostudies-literature

Near-Field Optical Drilling of Sub-? Pits in Thin Polymer Films.

Project description:Under UV illumination, polymer films can undergo chain scission and contract. Using this effect, tightly focused laser light is shown to develop runaway near-field concentration that drills sub-100 nm pits through a thin film. This subwavelength photolithography can be controlled in real time by monitoring laser scatter from the evolving holes, allowing systematic control of the void diameter. Our model shows how interference between the substrate and film together with near-field focusing by the evolving crevice directs this formation and predicts minimum pit sizes in films of 100 nm thickness on gold substrates. The smallest features so far are 60 nm diameter pits using 447 nm light focused onto polystyrene through a ×100 objective (NA = 0.8). Such arrays of pits can be easily used as masks for fabricating more complex nanostructures, such as plasmonic nanostructures and biomicrofluidic devices. This demonstration shows the potential for harnessing near-field feedback in optical direct-writing for nanofabrication.

| S-EPMC5578361 | biostudies-literature

Carboxymethyl Cellulose (CMC) Optical Fibers for Environment Sensing and Short-Range Optical Signal Transmission.

Project description:Optical fibers are a key component in modern photonics, where conventionally used polymer materials are derived from fossil-based resources, causing heavy greenhouse emissions and raising sustainability concerns. As a potential alternative, fibers derived from cellulose-based materials offer renewability, biocompatibility, and biodegradability. In the present work, we studied the potential of carboxymethyl cellulose (CMC) to prepare optical fibers with a core-only architecture. Wet-spun CMC hydrogel filaments were cross-linked using aluminum ions to fabricate optical fibers. The transmission spectra of fibers suggest that the light transmission window for cladding-free CMC fibers was in the range of 550-1350 nm, wherein the attenuation coefficient for CMC fibers was measured to be 1.6 dB·cm-1 at 637 nm. CMC optical fibers were successfully applied in touch sensing and respiratory rate monitoring. Finally, as a proof-of-concept, we demonstrate high-speed (150 Mbit/s) short-distance signal transmission using CMC fibers (at 1310 nm) in both air and water media. Our results establish the potential of carboxymethyl cellulose-based biocompatible optical fibers for highly demanding advanced sensor applications, such as in the biomedical domain.

| S-EPMC8778620 | biostudies-literature

The Optical Properties of Metal-Free Polymer Films with Self-Assembled Nanoparticles.

Project description:In this paper, it is reported that a metal-free and non-conjugated polymer, MA-PEG 8000-BADGE (MP8B), exhibits an antireflective property and substrate-dependent photoluminescence (SDP). MP8B was constructed from maleic anhydride, poly(ethylene glycol) and bisphenol-A diglycidyl ether. Self-assembled nanoparticles are found in MP8B and can prospectively act as scattering centers to improve light trapping and extraction. MP8B films prepared from MP8B solutions have been characterized by photoluminescence (PL), atomic force microscopy (AFM), tunnelling electron microscope (TEM), reflectance, transmittance, and UV-Vis absorption spectrum. MP8B films can suppress light reflection and enhance light transmission. The PL spectrum of MP8B film on ITO peaks at approximately 538 nm, spanning from 450 to 660 nm at a concentration of 25 mM. Meanwhile, the effects of concentration and substrate on the PL of MP8B films are also investigated in this study. Surface roughness becomes larger with concentration. A red shift of the PL spectrum is observed as solution concentration increases. Meanwhile, aggregation-caused quenching (ACQ) is insignificant. Moreover, the PL spectra of MP8B films show a substrate-dependent phenomenon due to dielectric screening. The optical band-gap energy of MP8B is approximately 4.05 eV. It is concluded that MP8B is a promising candidate for a host material, and its film can be utilized as a multifunctional layer (i.e., antireflective and light-scattering functions) for optoelectronic applications.

| S-EPMC8659585 | biostudies-literature

Significantly Increasing the Ductility of High Performance Polymer Semiconductors through Polymer Blending.

Project description:Polymer semiconductors based on donor-acceptor monomers have recently resulted in significant gains in field effect mobility in organic thin film transistors (OTFTs). These polymers incorporate fused aromatic rings and have been designed to have stiff planar backbones, resulting in strong intermolecular interactions, which subsequently result in stiff and brittle films. The complex synthesis typically required for these materials may also result in increased production costs. Thus, the development of methods to improve mechanical plasticity while lowering material consumption during fabrication will significantly improve opportunities for adoption in flexible and stretchable electronics. To achieve these goals, we consider blending a brittle donor-acceptor polymer, poly[4-(4,4-dihexadecyl-4H-cyclopenta[1,2-b:5,4-b']dithiophen-2-yl)-alt-[1,2,5]thiadiazolo[3,4-c]pyridine] (PCDTPT), with ductile poly(3-hexylthiophene). We found that the ductility of the blend films is significantly improved compared to that of neat PCDTPT films, and when the blend film is employed in an OTFT, the performance is largely maintained. The ability to maintain charge transport character is due to vertical segregation within the blend, while the improved ductility is due to intermixing of the polymers throughout the film thickness. Importantly, the application of large strains to the ductile films is shown to orient both polymers, which further increases charge carrier mobility. These results highlight a processing approach to achieve high performance polymer OTFTs that are electrically and mechanically optimized.

| S-EPMC5494703 | biostudies-literature

Optical Sensing of Humidity Using Polymer Top-Covered Bragg Stacks and Polymer/Metal Thin Film Structures.

Project description:Thin films with nanometer thicknesses in the range 100-400 nm are prepared from double hydrophilic copolymers of complex branched structures containing poly(N,N-dimethyl acrylamide) and poly(ethylene oxide) blocks and are used as humidity sensitive media. Instead of using glass or opaque wafer for substrates, polymer thin films are deposited on Bragg stacks and thin (30 nm) sputtered Au-Pd films thus bringing color for the colorless polymer/glass system and enabling transmittance measurements for humidity sensing. All samples are characterized by transmittance measurements at different humidity levels in the range from 5% to 90% relative humidity. Additionally, the humidity induced color change is studied by calculating the color coordinates at different relative humidity using measured spectra of transmittance or reflectance. A special attention is paid to the selection of wavelength(s) of measurements and discriminating between different humidity levels when sensing is performed by measuring transmittance at fixed wavelengths. The influence of initial film thickness, sensor architecture, and measuring configuration on sensitivity is studied. The potential and advantages of using top covered Bragg stacks and polymer/metal thin film structures as humidity sensors with simple optical read-outs are demonstrated and discussed.

| S-EPMC6630599 | biostudies-literature

Evanescent Wave Optical Trapping and Sensing on Polymer Optical Fibers for Ultra-Trace Detection of Glucose.

Project description:Graphene sensitization of glucose-imprinted polymer (G-IP)-coated optical fiber has been introduced as a new biosensor for evanescent wave trapping on the polymer optical fiber to detect low-level glucose. The developed sensor operates based on the evanescent wave modulation principle. Full characterization via atomic force microscopy (AFM), Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy, high-resolution transmission electron microscopy (HRTEM), and N2 adsorption/desorption of as-prepared G-IP-coated optical fibers was experimentally tested. Accordingly, related operational parameters such as roughness and diameter were optimized. Incorporating graphene into the G-IP not only steadily promotes the electron transport between the fiber surface and as-proposed G-IP but also significantly enhances the sensitivity by acting as a carrier for immobilizing G-IP with specific imprinted cavities. The sensor demonstrates a fast response time (5 s) and high sensitivity, selectivity, and stability, which cause a wide linear range (10-100 nM) and a low limit of detection (LOD = 2.54 nM). Experimental results indicate that the developed sensor facilitates online monitoring and remote sensing of glucose in biological liquids and food samples.

| S-EPMC7482082 | biostudies-literature

Effect of Oxygen Sputter Pressure on the Structural, Morphological and Optical Properties of ZnO Thin Films for Gas Sensing Application.

Project description:ZnO thin films were prepared on glass substrates at low (5 × 10-4 mbar) and high (3 × 10-3 mbar) sputter pressure using dc reactive magnetron sputtering. The structural, morphological, compositional and optical properties of the thin films were investigated. XRD patterns of both films confirmed the polycrystalline nature of the films with hexagonal Wurtzite structure. SEM study indicates that the surface of the film formed at high sputter pressure was more uniform, compact and porous in nature. From the EDAX analysis, no other characteristic peaks of other impurities were observed and the formation of single phase of ZnO was confirmed. From the study of photoluminescence, three peaks were observed, one strong near band-edge emission at 390 nm followed by weak and broad visible emissions around 420-480 nm. Room temperature ammonia sensing characteristics of ZnO nanothin films formed at higher sputter pressure were studied for different ammonia vapour concentration levels. The response of the Ammonia sensor at room temperature (30 °C) operation was observed to be of high sensitivity with quick response and recovery times.

| S-EPMC5747580 | biostudies-other

Injectable, dispersible polysulfone-polysulfone core-shell particles for optical oxygen sensing.

Project description:Injectable sensors can significantly improve the volume of critical biomedical information emerging from the human body in response to injury or disease. Optical oxygen sensors with rapid response times can be achieved by incorporating oxygen-sensitive luminescent molecules within polymeric matrices with suitably high surface area to volume ratios. In this work, electrospraying utilizes these advances to produce conveniently injectable, oxygen sensing particles made up of a core-shell polysulfone-polysulfone structure containing a phosphorescent oxygen-sensitive palladium porphyrin species within the core. Particle morphology is highly dependent on solvent identity and electrospraying parameters; DMF offers the best potential for the creation of uniform, sub-micron particles. Total internal reflection fluorescence (TIRF) microscopy confirms the existence of both core-shell structure and oxygen sensitivity. The dissolved oxygen response time is rapid (<0.30 s), ideal for continuous real-time monitoring of oxygen concentration. The incorporation of Pluronic F-127 surfactant enables efficient dispersion; selection of an appropriate electrospraying solvent (DMF) yields particles readily injected even through a <100 μm diameter needle.

| S-EPMC9455784 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data