Browse
Submit Data
Databases
API
Help

Dataset Information

21 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Water Recovery from Bioreactor Mixed Liquors Using Forward Osmosis with Polyelectrolyte Draw Solutions.

ABSTRACT: This paper reports on the use of forward osmosis (FO) with polyelectrolyte draw solutions to recover water from bioreactor mixed liquors. The work was motivated by the need for new regenerative water purification technologies to enable long-duration space missions. Osmotic membrane bioreactors may be an option for water and nutrient recovery in space if they can attain high water flux and reverse solute flux selectivity (RSFS), which quantifies the mass of permeated water per mass of draw solute that has diffused from the draw solution into a bioreactor. Water flux was measured in a direct flow system using wastewater from a municipal wastewater treatment plant and draw solutions prepared with two polyelectrolytes at different concentrations. The direct flow tests displayed a high initial flux (>10 L/m²/h) that decreased rapidly as solids accumulated on the feed side of the membrane. A test with deionized water as the feed revealed a small mass of polyelectrolyte crossover from the draw solution to the feed, yielding an RSFS of 80. Crossflow filtration experiments demonstrated that steady state flux above 2 L/m²·h could be maintained for 70 h following an initial flux decline due to the formation of a foulant cake layer. This study established that FO could be feasible for regenerative water purification from bioreactors. By utilizing a polyelectrolyte draw solute with high RSFS, we expect to overcome the need for draw solute replenishment. This would be a major step towards sustainable operation in long-duration space missions.

SUBMITTER: Raulerson CR

PROVIDER: S-EPMC8779258 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Using Reverse Osmosis Membrane at High Temperature for Water Recovery and Regeneration from Thermo-Responsive Ionic Liquid-Based Draw Solution for Efficient Forward Osmosis.

Project description:Forward osmosis (FO) membrane process is expected to realize energy-saving seawater desalination. To this end, energy-saving water recovery from a draw solution (DS) and effective DS regeneration are essential. Recently, thermo-responsive DSs have been developed to realize energy-saving water recovery and DS regeneration. We previously reported that high-temperature reverse osmosis (RO) treatment was effective in recovering water from a thermo-responsive ionic liquid (IL)-based DS. In this study, to confirm the advantages of the high-temperature RO operation, thermo-sensitive IL-based DS was treated by an RO membrane at temperatures higher than the lower critical solution temperature (LCST) of the DS. Tetrabutylammonium 2,4,6-trimethylbenznenesulfonate ([N4444][TMBS]) with an LCST of 58 °C was used as the DS. The high-temperature RO treatment was conducted at 60 °C above the LCST using the [N4444][TMBS]-based DS-lean phase after phase separation. Because the [N4444][TMBS]-based DS has a significantly temperature-dependent osmotic pressure, the DS-lean phase can be concentrated to an osmotic pressure higher than that of seawater at room temperature (20 °C). In addition, water can be effectively recovered from the DS-lean phase until the DS concentration increased to 40 wt%, and the final DS concentration reached 70 wt%. From the results, the advantages of RO treatment of the thermo-responsive DS at temperatures higher than the LCST were confirmed.

| S-EPMC8399973 | biostudies-literature

Performance Evaluation of 1-Cyclohexylpiperidine as a Draw Solute for Forward Osmosis Water Separation and CO<sub>2</sub> Recovery.

Project description:Membrane-based technologies, such as forward osmosis (FO), offer the advantage of treating water through a spontaneous process that requires minimal energy input while achieving favorable water permeability and selectivity. However, the FO process still has some challenges that need to be solved or improved to become entirely feasible. The main impediment for this technology is the recovery of the draw solute used to generate the osmotic potential in the process. In this paper, we discuss the use of a switchable polarity solvent, 1-cyclohexylpiperidine (CHP), as a draw solute that responds to external stimuli. Specifically, the miscibility of CHP can be switched by the presence of carbon dioxide (CO2) and is reversible by applying heat. Thus, in this study, the hydrophobic CHP is first converted to the hydrophilic ammonium salt (CHPH+), and its capability as a draw solution (DS) is thoroughly evaluated against the typical osmotic agent, sodium chloride (NaCl). Our results show that the water permeability across the thin film composite membrane increases by 69% when CHPH+ is used as the DS. Also, the water permeability when using different feed solutions: aqueous solutions of (a) urea and (b) NaCl were evaluated. In both cases, the CHPH+ generates water fluxes in the range of 65 ± 4 LMH and 69 ± 2 LMH, respectively. We then separate the diluted DS by applying 75 °C to the solution to recover the pure CHP and water. The results of this work provide a proof-of-concept of a CHP wastewater and desalination method via an FO process.

| S-EPMC7558060 | biostudies-literature

Application of Waste Glycerol as a Draw Solution for Forward Osmosis.

Project description:Waste glycerol generated during biofuel production accounts for ~10% of total biodiesel volume. Increasing the use of renewable energy sources, including so-called biodiesel, will significantly increase the amount of waste glycerol for disposal. One possible route for waste glycerol reuse is to use it as a draw solution in forward osmosis (FO). Glycerol solutions are particularly suited as FO draw solutions due to their high osmotic pressures. In this work, the effects of waste glycerol composition on FO draw solution osmotic pressures, as well as the effects of membrane type and linear flow velocities on FO water and reverse flux, were investigated. Those results indicated the feasibility of using waste glycerol as a draw solution in FO, allowing the reuse of significant amounts of this by-product.

| S-EPMC8780772 | biostudies-literature

Biofouling Mitigation Approaches during Water Recovery from Fermented Broth via Forward Osmosis.

Project description:Forward Osmosis (FO) is a promising technology that can offer sustainable solutions in the biorefinery wastewater and desalination fields, via low energy water recovery. However, microbial biomass and organic matter accumulation on membrane surfaces can hinder the water recovery and potentially lead to total membrane blockage. Biofouling development is a rather complex process and can be affected by several factors such as nutrient availability, chemical composition of the solutions, and hydrodynamic conditions. Therefore, operational parameters like cross-flow velocity and pH of the filtration solution have been proposed as effective biofouling mitigation strategies. Nevertheless, most of the studies have been conducted with the use of rather simple solutions. As a result, biofouling mitigation practices based on such studies might not be as effective when applying complex industrial mixtures. In the present study, the effect of cross-flow velocity, pH, and cell concentration of the feed solution was investigated, with the use of complex solutions during FO separation. Specifically, fermentation effluent and crude glycerol were used as a feed and draw solution, respectively, with the purpose of recirculating water by using FO alone. The effect of the abovementioned parameters on (i) ATP accumulation, (ii) organic foulant deposition, (iii) total water recovery, (iv) reverse glycerol flux, and (v) process butanol rejection has been studied. The main findings of the present study suggest that significant reduction of biofouling can be achieved as a combined effect of high-cross flow velocity and low feed solution pH. Furthermore, cell removal from the feed solution prior filtration may further assist the reduction of membrane blockage. These results may shed light on the challenging, but promising field of FO process dealing with complex industrial solutions.

| S-EPMC7693741 | biostudies-literature

Enhanced Forward Osmosis Desalination with a Hybrid Ionic Liquid/Hydrogel Thermoresponsive Draw Agent System.

Project description:Forward osmosis (FO) has emerged as a new technology for desalination and exhibits potentials for applications where reverse osmosis is incapable or uneconomical for treating streams with high salinity or fouling propensity. However, most of current draw agents in FO are salts and difficult to be recycled cost- and energy-effectively. In this work, we demonstrate a new and facile approach to efficiently recover water from the FO process with enhanced water purity by using a binary ion liquid/hydrogel system. The hybrid ion liquid/hydrogel draw solution system demonstrated in this work synergistically leverages the thermoresponsive properties of both the ionic liquid (IL) and hydrogel to improve the overall FO performance. Our findings corroborate that the hydrogel mitigates the water flux decline of the IL as the draw agent and provide a ready route to contiguously and effectively regenerate water from the FO process. Such a route allows for an efficient recovery of water from the draw solute/water mixture with enhanced water purity, compared with conventional thermal treating of lower critical solution temperature IL draw solute/water. Furthermore, hydrogels can be used in a continuous and readily recyclable process to recover water without heating the entire draw solute/water mixture. Our design principles open the door to use low-grade/waste heat or solar energy to regenerate draw agents and potentially reduce energy in the FO process considerably.

| S-EPMC6648795 | biostudies-literature

Continuous electrochemical water splitting from natural water sources via forward osmosis.

Project description:Electrochemical water splitting stores energy as equivalents of hydrogen and oxygen and presents a potential route to the scalable storage of renewable energy. Widespread implementation of such energy storage, however, will be facilitated by abundant and accessible sources of water. We describe herein a means of utilizing impure water sources (e.g., saltwater) for electrochemical water splitting by leveraging forward osmosis. A concentration gradient induces the flow of water from an impure water source into a more concentrated designed electrolyte. This concentration gradient may subsequently be maintained by water splitting, where rates of water influx (i.e., forward osmosis) and effective outflux (i.e., water splitting) are balanced. This approach of coupling forward osmosis to water splitting allows for the use of impure and natural sources without pretreatment and with minimal losses in energy efficiency.

| S-EPMC7936378 | biostudies-literature

Pharmaceutical concentration using organic solvent forward osmosis for solvent recovery.

Project description:The organic solvent forward osmosis (OSFO) process can simultaneously concentrate the active pharmaceutical ingredients (APIs) and recover the organic solvents. Here we demonstrate and evaluate an OSFO process for solvent recovery. In this demonstration, OSFO was conducted in different solvents with different draw solutes. The OSFO process shows rejections >98% when recovering organic solvents from different feed solutions, even when the feed concentration is as high as 20?wt%. More importantly, all systems exhibit relatively low ratios of reverse solute flux to solvent flux, indicating that the adverse effects of using hazardous draw solutions could be minimized. Nevertheless, the use of non-hazardous draw solutes such as citric acid is highly recommended to remove any potential risk, and it has been demonstrated. Herein, the OSFO process is a promising technology for solvent recovery as it possesses a reasonable solvent flux, low reverse solute flux and requires no external pressure.

| S-EPMC5897543 | biostudies-literature

Behavior of Weak Polyelectrolyte Brushes in Mixed Salt Solutions.

Project description:Hydrophilic and hydrophobic weak polybasic brushes immersed in aqueous solutions of mixed salt counterions are considered using a mean-field numerical self-consistent field approach. On top of the solvent quality of the polymer, the counterion-solvent interactions are accounted for by implementing Flory-Huggins interaction parameters. We show that ion specificity within the brush can bring about large changes in conformation. It is found that the collapse transition of hydrophobic, weak polyelectrolyte brushes features an intermediate two-phase state wherein a subset of chains are collapsed in a dense layer at the substrate, while the remainder of chains are well-solvated and strongly stretched away from the it. Besides pH and ionic strength, solvent quality of counterions and the composition of ions in the solvent are important control parameters for the behavior of polyelectrolyte brushes. Increasingly hydrophobic counterions penetrate deeper within the brush and stabilize the collapsed region, while hydrophilic counterions do the opposite.

| S-EPMC5814957 | biostudies-literature

Efficiently Combining Water Reuse and Desalination through Forward Osmosis-Reverse Osmosis (FO-RO) Hybrids: A Critical Review.

Project description:Forward osmosis (FO) is a promising membrane technology to combine seawater desalination and water reuse. More specifically, in a FO-reverse osmosis (RO) hybrid process, high quality water recovered from the wastewater stream is used to dilute seawater before RO treatment. As such, lower desalination energy needs and/or water augmentation can be obtained while delivering safe water for direct potable reuse thanks to the double dense membrane barrier protection. Typically, FO-RO hybrid can be a credible alternative to new desalination facilities or to implementation of stand-alone water reuse schemes. However, apart from the societal (public perception of water reuse for potable application) and water management challenges (proximity of wastewater and desalination plants), FO-RO hybrid has to overcome technical limitation such as low FO permeation flux to become economically attractive. Recent developments (i.e., improved FO membranes, use of pressure assisted osmosis, PAO) demonstrated significant improvement in water flux. However, flux improvement is associated with drawbacks, such as increased fouling behaviour, lower rejection of trace organic compounds (TrOCs) in PAO operation, and limitation in FO membrane mechanical resistance, which need to be better considered. To support successful implementation of FO-RO hybrid in the industry, further work is required regarding up-scaling to apprehend full-scale challenges in term of mass transfer limitation, pressure drop, fouling and cleaning strategies on a module scale. In addition, refined economics assessment is expected to integrate fouling and other maintenance costs/savings of the FO/PAO-RO hybrid systems, as well as cost savings from any treatment step avoided in the water recycling.

| S-EPMC5041028 | biostudies-other

Hole-Type Spacers for More Stable Shale Gas-Produced Water Treatment by Forward Osmosis.

Project description:An appropriate spacer design helps in minimizing membrane fouling which remains the major obstacle in forward osmosis (FO) systems. In the present study, the performance of a hole-type spacer (having holes at the filament intersections) was evaluated in a FO system and compared to a standard spacer design (without holes). The hole-type spacer exhibited slightly higher water flux and reverse solute flux (RSF) when Milli-Q water was used as feed solution and varied sodium chloride concentrations as draw solution. During shale gas produced water treatment, a severe flux decline was observed for both spacer designs due to the formation of barium sulfate scaling. SEM imaging revealed that the high shear force induced by the creation of holes led to the formation of scales on the entire membrane surface, causing a slightly higher flux decline than the standard spacer. Simultaneously, the presence of holes aided to mitigate the accumulation of foulants on spacer surface, resulting in no increase in pressure drop. Furthermore, a full cleaning efficiency was achieved by hole-type spacer attributed to the micro-jets effect induced by the holes, which aided to destroy the foulants and then sweep them away from the membrane surface.

| S-EPMC7824311 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data