Diametric calix[6]arene-based phosphine gold(I) cavitands
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ABSTRACT: We report the synthesis and characterization, in low polarity solvents, of a novel class of diametric phosphine gold(I) cavitands characterized by a 1,2,3-alternate geometry. Preliminary catalytic studies were performed on a model cycloisomerization of 1,6-enynes as a function of the relative orientation of the bonded gold(I) nuclei with respect to the macrocyclic cavity.
SUBMITTER: Giovanardi G
PROVIDER: S-EPMC8848346 | biostudies-literature | 2022 Jan
REPOSITORIES: biostudies-literature
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