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Enhanced Removal of Malachite Green Using Calcium-Functionalized Magnetic Biochar.

ABSTRACT: To efficiently remove malachite green (MG), a novel calcium-functionalized magnetic biochar (Ca/MBC) was fabricated via a two-step pyrolysis method. Iron-containing oxides endowed the target complexes with magnetic properties, especially the chemotactic binding ability with MG, and the addition of calcium significantly changed the morphology of the material and improved its adsorption performance, especially the chemotactic binding ability with MG, which could be confirmed through FTIR, XPS, and adsorption experiments. Electrostatic adsorption, ligand exchange, and hydrogen bonding acted as essential drivers for an enhanced adsorption process, and the maximum theoretical adsorption capacity was up to 12,187.57 mg/g. Ca/MBC maintained a higher adsorption capacity at pH = 4-12, and after five adsorption-desorption cycles, the adsorption capacity and adsorption rate of MG remained at 1424.2 mg/g and 71.21%, highlighting the advantages of Ca/MBC on adsorbing MG. This study suggests that biochar can be modified by a green synthesis approach to produce calcium-functionalized magnetic biochar with excellent MG removal capacity. The synthetic material can not only remove pollutants from water but also provide an efficient way for soil remediation.

SUBMITTER: Wang P

PROVIDER: S-EPMC8954663 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature

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Enhanced Removal of Malachite Green Using Calcium-Functionalized Magnetic Biochar.

Wang Pengjie P Chen Wei W Zhang Rui R Xing Yanfeng Y

International journal of environmental research and public health 20220310 6

To efficiently remove malachite green (MG), a novel calcium-functionalized magnetic biochar (Ca/MBC) was fabricated via a two-step pyrolysis method. Iron-containing oxides endowed the target complexes with magnetic properties, especially the chemotactic binding ability with MG, and the addition of calcium significantly changed the morphology of the material and improved its adsorption performance, especially the chemotactic binding ability with MG, which could be confirmed through FTIR, XPS, and ...[more]

PMID: 35328937

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Project description:Phytogenic magnetic nanoparticles (PMNPs) were fabricated using plant leaves' extract of Fraxinus chinensis Roxb. and then, the surfaces of the PMNPs were functionalized by 3-mercaptopropionic acid (3-MPA) to investigate the adsorptive removal of the toxic dye malachite green (MG) from aqueous solutions. The preparation and coating of 3-MPA on the surface of the PMNPs was confirmed and characterized using different techniques, which are UV-visible spectroscopy, Fourier transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD), scanning electron microscopy with integrated energy dispersive X-ray analysis (SEM-EDX), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), vibrating sample magnetometry (VSM), Brunauer-Emmett-Teller (BET) analysis and thermogravimetric analysis (TGA). The hysteresis loops of 3-MPA@PMNPs depicted an excellent superparamagnetic nature with saturation magnetization values of 50.95 emu g-1. The prepared material showed the highest adsorptive rate (98.57% MG removal within 120 min) and an estimated comparable adsorptive capacity of 81.2 mg g-1 at 25 °C. The experimental data were well fitted to the Langmuir isotherm, indicating the monolayer adsorption of MG onto 3-MPA@PMNPs. Furthermore, the kinetic data agreed well with the pseudo-second-order model, indicating the removal of MG by chemisorption and/or ion-exchange mechanism. Thermodynamic study confirmed that the adsorption of MG was exothermic and spontaneous. The high adsorptive removal of the dye not only persisted over a wide pH range (6-12), but the material also demonstrated high selectivity in the presence of co-existing ions (i.e. Pd2+ and Cd2+) along with the fastest separation times (35 s) from aqueous solutions. The recovered adsorbent (3-MPA@PMNPs) was reused five times and maintained a removal efficiency of more than 85%. Therefore, the prepared novel 3-MPA@PMNPs can be employed as an alternative low-cost sorbent material for the removal cationic dyes from textile wastewater. In addition, this green nanotechnology/strategy can easily be implemented in low-economy countries for wastewater treatment.

Project description:This study assessed the efficacy of adsorption for eliminating the agricultural pesticide cypermethrin (CP) from wastewater using various adsorbents: silica, malachite, and magnetite. Magnetic nanocomposites (NCs) (with varying amounts of Fe3O4 0.1, 0.25, 0.5, 1.0, and 1.5 wt/wt %) were synthesized, including Fe3O4 nanoparticles (NPs), bicomposites, and tricomposites, calcined at 300 and 500 °C, and then tested for CP removal. The study was conducted in two phases, with the objective of initially assessing how effectively each individual NP performed and then evaluating how effectively the NCs performed when used for the adsorption of CP. Notably, the Fe3O4-malachite combination exhibited superior CP removal, with the 0.25-Fe-M NC achieving the highest adsorption at 635.4 mg/g. This success was attributed to the large surface area, magnetic properties of Fe3O4, and adsorption capabilities of malachite. The Brunauer-Emmett-Teller (BET) isotherm analysis indicated that the NCs had potential applications in adsorption and separation processes. The scanning electron microscopy and transmission electron microscopy revealed the spherical, irregular shaped morphology of the synthesized NPs and NCs. However, the X-ray diffraction (XRD) pattern of surface functionalized materials such as surface functionalized malachite [Cu2CO3(OH)2] with Fe3O4 and SiO2 may be complicated by the specific functionalization method used and the relative amounts and crystallographic orientations of each component. Therefore, careful interpretation and analysis of the XRD pattern, along with other techniques, are necessary for accurate identification and characterization of the functionalized material. The originality of this study lies in its comprehensive investigation of several adsorbents and NCs for CP removal at neutral pH. The innovation stems from the synergistic action of Fe3O4 and malachite, which results in improved CP removal due to their combined surface properties and magnetic characteristics. The application of magnetic NCs in adsorption and separation, as validated by BET isotherm analysis, highlights the potential breakthrough in addressing pesticide contamination.

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Enhanced Removal of Malachite Green Using Calcium-Functionalized Magnetic Biochar.

Publications

Enhanced Removal of Malachite Green Using Calcium-Functionalized Magnetic Biochar.

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