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Fabrication of a zinc oxide/alginate (ZnO/Alg) bionanocomposite for enhanced dye degradation and its optimization study.

ABSTRACT: This paper studies a new response surface methodology (RSM) based on the central composite design (CCD) modeling method to optimize the photocatalytic degradation of methylene blue (MB) and methyl orange (MO) by using a synthesized ZnO/Alg bionanocomposite under UV irradiation. ZnO with different content of sodium alginate (Alg) (10, 20, and 30% by weight) has been synthesized by a one-step sol-gel method. Zinc oxide (ZnO) nanoparticles were impregnated on the alginate polymer. Various characterization techniques were used to describe the physical and chemical properties of each catalyst such as XRD, FTIR, UV-vis, PL, FESEM, Raman, and BET. The optimal catalyst for MB and MO photocatalytic degradation process was discussed mathematically as a function of catalyst dose, irradiation time, and MB and MO concentration, which was modeled by CCD-RSM based on a statistical model (quadratic regression) and an optimization process (ANOVA analysis). The photocatalytic degradation efficiency of 98% was achieved for the optimal conditions of a dye concentration of 20 mg L^-1, the catalyst dose of 0.34 g L^-1, and an irradiation time of 90 min at pH 6. The measurement result (R ² = 0.9901) showed that the considered model is very suitable, and the selected CCD-RSM successfully optimized the photodegradation conditions of MB and MO.

SUBMITTER: Siddiqui VU

PROVIDER: S-EPMC8982159 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature

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Fabrication of a zinc oxide/alginate (ZnO/Alg) bionanocomposite for enhanced dye degradation and its optimization study.

Siddiqui Vasi Uddin VU Ansari Afzal A Ansari M Taazeem MT Akram Md Khursheed MK Siddiqi Weqar Ahmad WA

RSC advances 20220302 12

This paper studies a new response surface methodology (RSM) based on the central composite design (CCD) modeling method to optimize the photocatalytic degradation of methylene blue (MB) and methyl orange (MO) by using a synthesized ZnO/Alg bionanocomposite under UV irradiation. ZnO with different content of sodium alginate (Alg) (10, 20, and 30% by weight) has been synthesized by a one-step sol-gel method. Zinc oxide (ZnO) nanoparticles were impregnated on the alginate polymer. Various character ...[more]

PMID: 35424670

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Project description:Photocatalysts suffer from a lack of separation of photogenerated excitons due to the fast recombination of charge carriers, so a strong synergistic effect exhibited by photocatalysts is promising for effective photocatalysis. Herein, we have synthesized efficient visible light functionalized graphene oxide nanosheet (FGS)/ZnO nanocomposite photocatalysts via a simple and economical approach with large scale production for practical applications. A series of nanocomposites (FGS/ZnO NCs) with different amounts by weight of graphene oxide (GO) have been synthesized via a facile solution route followed by calcination under environmental conditions. The phase, purity and morphological studies of the synthesized FGS/ZnO NCs were carried out using powder X-ray diffraction (XRD) and transmission electron microscopy (TEM). The optical properties were studied using UV-visible diffuse reflectance spectroscopy (DRS) and photoluminescence spectroscopy (PL). XRD results confirm the formation of a pure phase of ZnO in the FGS/ZnO NCs and TEM results show strongly adhered ZnO NPs on the surface of the FGS. DRS results confirm the extension of light absorption in the visible region while PL results confirm the effective separation of charge carriers in 0.09 wt% FGS/ZnO NCs. The synthesized photocatalyst efficiently degrades carcinogenic safranin-T dye under visible light illumination which is reported for the first time using FGS/ZnO nanocomposites. Photocatalytic studies confirm the higher photocatalytic activity of 0.09 wt% FGS/ZnO NCs (about 94.5%) towards the photodegradation of safranin-T dye in aqueous solution under visible light. The improved photocatalytic activity of 0.09 wt% FGS/ZnO NCs can be ascribed to the integrative synergistic effects of the enhanced adsorption capacity of safranin-T dye, effective separation of photogenerated excitons and effective interfacial hybridization of FGS and ZnO NCs. The generation of reactive oxygen species was confirmed using terephthalic acid as a probe molecule and a scavenger test was conducted in presence of histidine.

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Fabrication of a zinc oxide/alginate (ZnO/Alg) bionanocomposite for enhanced dye degradation and its optimization study.

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Fabrication of a zinc oxide/alginate (ZnO/Alg) bionanocomposite for enhanced dye degradation and its optimization study.

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