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Corrosion comparison of free and roller surfaces of Fe₇₀Si₈B₁₂Nb₁₀ amorphous ribbon.

ABSTRACT: The corrosion resistance of the free surface (FS) and roller surface (RS) of Fe₇₀Si₈B₁₂Nb₁₀ amorphous ribbon was systematically compared in simulated seawater (0.6 M NaCl). The electrochemical method and scanning electron microscopy showed that the FS corrosion resistance was higher than that of the RS. XPS etching and Mott-Schottky tests indicated that the passivation films on the FS and RS were divided into outer and inner layers. In the spinning process, the elements with a higher atomic mass tend to segregate toward the FS, while the elements with a lower atomic mass segregate toward the RS. These results provide data that can be used to improve the quality of melt spinning ribbons and to optimize the manufacturing of involved electric devices.

SUBMITTER: Zhang H

PROVIDER: S-EPMC9041945 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature

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Corrosion comparison of free and roller surfaces of Fe70Si8B12Nb10 amorphous ribbon.

Zhang H H Yan Z C ZC Chen Q Q Qi Z G ZG Feng Y Y Liu H Z HZ Li X Y XY Wang W M WM

RSC advances 20210929 51

The corrosion resistance of the free surface (FS) and roller surface (RS) of Fe70Si8B12Nb10 amorphous ribbon was systematically compared in simulated seawater (0.6 M NaCl). The electrochemical method and scanning electron microscopy showed that the FS corrosion resistance was higher than that of the RS. XPS etching and Mott-Schottky tests indicated that the passivation films on the FS and RS were divided into outer and inner layers. In the spinning pro ...[more]

PMID: 35495509

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Project description:Phosphorus (P) is a fundamental element for whatever form of life, in the same way as the other biogenic macroelements (SONCH). The prebiotic origin of P is still a matter of debate, as the phosphates present on earth are trapped in almost insoluble solid matrixes (apatites) and, therefore, hardly available for inclusion in living systems in the prebiotic era. The most accepted theories regard a possible exogenous origin during the Archean Era, through the meteoritic bombardment, when tons of reactive P in the form of phosphide ((Fe,Ni)3P, schreibersite mineral) reached the primordial earth, reacting with water and providing oxygenated phosphorus compounds (including phosphates). In the last 20 years, laboratory experiments demonstrated that the corrosion process of schreibersite by water indeed leads to reactive phosphates that, in turn, react with other biological building blocks (nucleosides and simple sugars) to form more complex molecules (nucleotides and complex sugars). In the present paper, we study the water corrosion of different crystalline surfaces of schreibersite by means of periodic DFT (density functional theory) simulations. Our results show that water adsorbs molecularly on the most stable (110) surface but dissociates on the less stable (001) one, giving rise to further reactivity. Indeed, subsequent water adsorptions, up to the water monolayer coverage, show that, on the (001) surface, iron and nickel atoms are the first species undergoing the corrosion process and, in a second stage, the phosphorus atoms also get involved. When adsorbing up to three and four water molecules per unit cell, the most stable structures found are the phosphite and phosphate forms of phosphorus, respectively. Simulation of the vibrational spectra of the considered reaction products revealed that the experimental band at 2423 cm-1 attributed to the P-H stretching frequency is indeed predicted for a phosphite moiety attached to the schreibersite (001) surface upon chemisorption of up to three water molecules.

Dataset Information

Corrosion comparison of free and roller surfaces of Fe₇₀Si₈B₁₂Nb₁₀ amorphous ribbon.

Publications

Corrosion comparison of free and roller surfaces of Fe<sub>70</sub>Si<sub>8</sub>B<sub>12</sub>Nb<sub>10</sub> amorphous ribbon.

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