Solid-state synthesis of few-layer cobalt-doped MoS₂ with CoMoS phase on nitrogen-doped graphene driven by microwave irradiation for hydrogen electrocatalysis.

ABSTRACT: The high catalytic activity of cobalt-doped MoS₂ (Co-MoS₂) observed in several chemical reactions such as hydrogen evolution and hydrodesulfurization, among others, is mainly attributed to the formation of the CoMoS phase, in which Co occupies the edge-sites of MoS₂. Unfortunately, its production represents a challenge due to limited cobalt incorporation and considerable segregation into sulfides and sulfates. We, therefore, developed a fast and efficient solid-state microwave irradiation synthesis process suitable for producing thin Co-MoS₂ flakes (∼3-8 layers) attached on nitrogen-doped reduced graphene oxide. The CoMoS phase is predominant in samples with up to 15 at% of cobalt, and only a slight segregation into cobalt sulfides/sulfates is noticed at larger Co content. The Co-MoS₂ flakes exhibit a large number of defects resulting in wavy sheets with significant variations in interlayer distance. The catalytic performance was investigated by evaluating the activity towards the hydrogen evolution reaction (HER), and a gradual improvement with increased amount of Co was observed, reaching a maximum at 15 at% with an overpotential of 197 mV at -10 mA cm^-2, and a Tafel slope of 61 mV dec^-1. The Co doping had little effect on the HER mechanism, but a reduced onset potential and charge transfer resistance contributed to the improved activity. Our results demonstrate the feasibility of using a rapid microwave irradiation process to produce highly doped Co-MoS₂ with predominant CoMoS phase, excellent HER activity, and operational stability.

SUBMITTER: Fan J 

PROVIDER: S-EPMC9056874 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature