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Fish-scale-derived carbon dots as efficient fluorescent nanoprobes for detection of ferric ions.


ABSTRACT: Herein, highly fluorescent carbon dots (CDs) with the incorporation of N and O functionalities were prepared through a facile and cost-effective hydrothermal reaction using fish scales of the crucian carp as the precursor. The as-prepared CDs exhibit strong fluorescent emissions at 430 nm with a relative quantum yield of 6.9%, low cytotoxicity, and robust fluorescence stability against photobleaching and good ionic strength. More significantly, the fluorescence of these CDs can be effectively and selectively quenched by Fe3+ ions, which enables the application of CDs as fluorescent Fe3+ nanoprobes with a linear range of 1-78 μmol L-1 and a detection limit of 0.54 μmol L-1. The proposed fluorescent CD nanoprobes can also be used for the assay of spiked Fe3+ in real water samples and human serums with high recoveries and low standard deviations. Hence, CDs can be potentially applied as safe and reliable fluorescent nanoprobes for environmental and clinical Fe3+ analyses.

SUBMITTER: Zhang Y 

PROVIDER: S-EPMC9059499 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature

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Fish-scale-derived carbon dots as efficient fluorescent nanoprobes for detection of ferric ions.

Zhang Yi Y   Gao Zhiyong Z   Yang Xue X   Chang Jiuli J   Liu Ziyan Z   Jiang Kai K  

RSC advances 20190109 2


Herein, highly fluorescent carbon dots (CDs) with the incorporation of N and O functionalities were prepared through a facile and cost-effective hydrothermal reaction using fish scales of the crucian carp as the precursor. The as-prepared CDs exhibit strong fluorescent emissions at 430 nm with a relative quantum yield of 6.9%, low cytotoxicity, and robust fluorescence stability against photobleaching and good ionic strength. More significantly, the fluorescence of these CDs can be effectively an  ...[more]

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