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Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins.

ABSTRACT: Chiral 1,2-diols with a high yield could be directly prepared from asymmetric di-hydroxylation of olefins via an eco-friendly and enduring catalyst, in which abundant "chiral pools" of polyoxometalate-ionic liquid were target-designed into the silicic framework (POM-ILS) and well stabilized in aqueous media.

SUBMITTER: Liang D

PROVIDER: S-EPMC9060907 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature

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Well-confined polyoxometalate-ionic liquid in silicic framework for environmentally friendly asymmetric di-hydroxylation of olefins.

Liang Dong D Wang Yan Y Wang Sifan S Song Chengkun C Shi Yonghe Y Liu Qinghao Q Zhu Hailin H Li Xia X Liu Laishuan L Zhu Na N

RSC advances 20190219 11

Chiral 1,2-diols with a high yield could be directly prepared from asymmetric di-hydroxylation of olefins <i>via</i> an eco-friendly and enduring catalyst, in which abundant "chiral pools" of polyoxometalate-ionic liquid were target-designed into the silicic framework (POM-ILS) and well stabilized in aqueous media. ...[more]

PMID: 35517290

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