Halide exchange studies of novel Pd(ii) NNN-pincer complexes.
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ABSTRACT:
SUBMITTER: Kuyuldar S
PROVIDER: S-EPMC9070094 | biostudies-literature | 2019 Aug
REPOSITORIES: biostudies-literature
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Halide exchange studies of novel Pd(ii) NNN-pincer complexes.
Kuyuldar Seher S Burda Clemens C Connick William B WB
RSC advances 20190815 44
Palladium(ii) complexes with an NNN type pincer ligand (pip<sub>2</sub>NNN = 2,6-bis(piperdyl-methyl)pyridine) are synthesized and characterized. Electronic and <sup>1</sup>H NMR spectra point to decreasing filled/filled repulsions between the dπ(Pd) orbitals and the halide lone pair orbitals along the Cl < Br < I series. For all complexes, the most downfield α-piperidyl resonance of the pip<sub>2</sub>NNN ligand is sensitive to changes in the coordinated halide while the <i>meta</i>-pyridyl and ...[more]
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