Ontology highlight
ABSTRACT:
SUBMITTER: Monger LJ
PROVIDER: S-EPMC8433849 | biostudies-literature | 2021 Aug
REPOSITORIES: biostudies-literature
Monger Lindsey J LJ Razinkov Dmitrii D Bjornsson Ragnar R Suman Sigridur G SG
Molecules (Basel, Switzerland) 20210826 17
The aqueous synthesis of Pd(II) complexes with alkylated tripeptides led to the hydrolysis of the peptides at low pH values and mixtures of complexed peptides were formed. A non-aqueous synthetic route allowed the formation and isolation of single products and their characterization. Pd(II) complexes with α-Asp(OR)AlaGly(OR), β-Asp(OR)AlaGly(OR), and TrpAlaGly(OR) (R = H or alkyl) as tri and tetradentate chelates were characterized. The tridentate coordination mode was accompanied by a fourth mo ...[more]