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Methane adsorption and methanol desorption of copper modified boron silicate.

ABSTRACT: Boron silicate (BS) with a chabazite framework structure was synthesised using a direct route and rigorously characterized before it was ion-exchanged with copper to form Cu-BS. Employing in situ infrared spectroscopy, we show that Cu-BS is capable of oxidising methane to methoxy species and methanol interacts with the boron sites without deprotonation.

SUBMITTER: Wang X

PROVIDER: S-EPMC9088827 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature

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Methane adsorption and methanol desorption of copper modified boron silicate.

Wang Xueting X Shishkin Alexander A Hemmingsson Felix F Skoglundh Magnus M Martinez-Casado Francisco Javier FJ Bock Lorenz L Idström Alexander A Nordstierna Lars L Härelind Hanna H Carlsson Per-Anders PA

RSC advances 20181026 63

Boron silicate (BS) with a chabazite framework structure was synthesised using a direct route and rigorously characterized before it was ion-exchanged with copper to form Cu-BS. Employing <i>in situ</i> infrared spectroscopy, we show that Cu-BS is capable of oxidising methane to methoxy species and methanol interacts with the boron sites without deprotonation. ...[more]

PMID: 35558450

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