Ontology highlight
ABSTRACT:
SUBMITTER: Yang Y
PROVIDER: S-EPMC9130751 | biostudies-literature | 2022
REPOSITORIES: biostudies-literature
Yang Yu Y Jiang Nan N Mei Yuling Y Ding Zekun Z Zhang Jianbo J
Frontiers in chemistry 20220511
A sustainable magnetic core-shell nanocatalyst Fe<sub>3</sub>O<sub>4</sub>@C@Fe(III) was successfully applied in the synthesis of a series of 2-nitro-2,3-unsaturated <i>O</i>-glycosides with excellent yields (up to 89%) and high stereoselectivity (α:β > 19:1). The substrate ranges are widely applicable, including different kinds of alcohols and even structurally complex acceptors. In addition, phenols could be applied in good yields. Moreover, the catalyst could be easily separated from the reac ...[more]