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Synthesis of 2-Nitro-2,3-Unsaturated Glycosides by a Nanomagnetic Catalyst Fe3O4@C@Fe(III).


ABSTRACT: A sustainable magnetic core-shell nanocatalyst Fe3O4@C@Fe(III) was successfully applied in the synthesis of a series of 2-nitro-2,3-unsaturated O-glycosides with excellent yields (up to 89%) and high stereoselectivity (α:β > 19:1). The substrate ranges are widely applicable, including different kinds of alcohols and even structurally complex acceptors. In addition, phenols could be applied in good yields. Moreover, the catalyst could be easily separated from the reaction by the application of an external magnetic force and reused a minimum of five times without any significant decrease in catalytic performance.

SUBMITTER: Yang Y 

PROVIDER: S-EPMC9130751 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature

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Synthesis of 2-Nitro-2,3-Unsaturated Glycosides by a Nanomagnetic Catalyst Fe<sub>3</sub>O<sub>4</sub>@C@Fe(III).

Yang Yu Y   Jiang Nan N   Mei Yuling Y   Ding Zekun Z   Zhang Jianbo J  

Frontiers in chemistry 20220511


A sustainable magnetic core-shell nanocatalyst Fe<sub>3</sub>O<sub>4</sub>@C@Fe(III) was successfully applied in the synthesis of a series of 2-nitro-2,3-unsaturated <i>O</i>-glycosides with excellent yields (up to 89%) and high stereoselectivity (α:β > 19:1). The substrate ranges are widely applicable, including different kinds of alcohols and even structurally complex acceptors. In addition, phenols could be applied in good yields. Moreover, the catalyst could be easily separated from the reac  ...[more]

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