Solid-state molecular oxygen activation using ball milling and a piezoelectric material for aerobic oxidation of thiols.
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ABSTRACT: The agitation of BaTiO3 via ball milling converts mechanical energy into electrical energy, leading to the reduction of molecular oxygen via a single electron transfer pathway analogous to the photocatalytic reaction. This mechanoredox strategy for the oxidative coupling of thiols could eliminate waste and develop a recyclable methodology to accomplish organic transformations in a greener fashion, exhibiting promising potential for large-scale chemical manufacturing.
SUBMITTER: Wang G
PROVIDER: S-EPMC9214485 | biostudies-literature |
REPOSITORIES: biostudies-literature
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