Browse
Submit Data
Databases
API
Help

Dataset Information

23 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

The Aggregation of Destabilized Ag Triangular Nanoplates and Its Application in Detection of Thiram Residues.

ABSTRACT: An aggregation or assembly of Ag triangular nanoplates (Ag TNPs) can cause dramatic changes in their optical properties, which is widely used in applications in the field of sensing. The assembly forms of nanoparticles are crucial for obtaining sensitive sensing signals, but it is unknown what kind of assembly dominates the aggregated Ag TNPs in aqueous solutions. Herein, using thiram-induced Ag TNP aggregation as a model, six different assembly models were established, including three planar (side-by-side, side-to-tip, and tip-to-tip) assemblies and three tridimensional (plane-to-plane, plane-to-tip, and plane-to-side) assemblies. The corresponding optical properties were then investigated. Both theoretical and experimental findings indicate that three-dimensional assemblies, especially plane-to-plane assembly, dominate the Ag TNPs aggregation solution, causing a blue shift of the absorption spectrum. Analysis of charge distribution patterns in Ag TNPs indicates that such a blue shift is caused by the electrostatic repulsive force in plane-to-plane assembly. Thus, we propose a simple colorimetric method for thiram detection using Ag TNPs as an indicator. The method exhibits a selective and sensitive response to thiram with a limit of detection of 0.13 μM in the range of 0.2-0.5 μM, as well as excellent performance in real samples like wheat.

SUBMITTER: Zhang C

PROVIDER: S-EPMC9268207 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Oriented attachment mechanism of triangular Ag nanoplates: a molecular dynamics study.

Project description:We use molecular-dynamics simulations to probe the experimentally observed aggregation of PVP-covered triangular Ag nanoplates to form 2D sheets in solution. We find lateral plate attachment is the most favorable aggregation pathway - consistent with experiment. The mechanism is general and suggests new processing strategies for creating 2D architectures in solution-phase syntheses.

| S-EPMC9418432 | biostudies-literature

Triangular Silver Nanoplates as a Bioanalytical Tool: Potential COVID-19 Detection.

Project description:Nanotechnology offers new possibilities in molecular diagnostics, with nanoparticles gaining attention as biosensor upgrades. This study evaluates gold-coated silver nanoplates coated with PEG for enhanced protection, aiming to detect Spike protein with higher sensitivity, and emphasizes the importance of considering complex environments and appropriate controls for specific binding and accurate analysis. The sensitivity of antibody-coated PEGAuTSNPs as tools for immunoassays is demonstrated through fibronectin (Fn)- anti-fibronectin binding within an isolated extracellular matrix as a complex and native environment of Fn. Moreover, the optimal functionalization volume of Spike protein was determined (4 µg/mL of PEGAuTSNP). Anti-Spike was added to confirm binding, while the TJP1 protein was used as a negative control. The same experiment was used in the presence of horse serum to simulate a complex environment. According to Localized Surface Plasmon Resonance analysis and Dynamic Light Scattering size measurements, anti-Spike exhibited a stronger affinity for the nanoplates, causing TJP1 to be replaced by the antibody on the nanoplates' surface. Future research will involve exploring alternative complex environments, filtering larger molecules, and the optimization of immunoassay performance.

| S-EPMC10418913 | biostudies-literature

Spectral dependence of third-order susceptibility of Au triangular nanoplates.

Project description:We experimentally investigated the spectral dependence of the third-order susceptibility [Formula: see text] of Au triangular nanoplates in a broad wavelength region (400-1,000 nm). Complex shaped plasmonic nanoparticles provide a promising route to achieve control of their optical properties at the nanoscale. However, little is known about the effects of geometrical parameters to the optical nonlinearities and underlying mechanisms of the plasmon modes. Here, we obtained the [Formula: see text] of Au triangular nanoplates featuring a narrow plasmon resonance that is tunable in the visible and near-IR regions. This work demonstrates that the plasmonic triangular nanoplates simultaneously shows self-focusing and -defocusing, and saturable and reverse-saturable absorption properties at specific wavelength regions. Maximum amplitudes of real and imaginary components are - 6.8 × 10-18 m2/V2 at 668 nm and - 6.7 × 10-18 m2/V2 at 646 nm, respectively. Spectral dependence of the quantity [Formula: see text] enables comparison between different shaped plasmonic NPs to boost active plasmonic applications performance.

| S-EPMC7431854 | biostudies-literature

Regioselective DNA Modification and Directed Self-Assembly of Triangular Gold Nanoplates.

Project description:As a class of emerging nanoparticles, gold nanotriangles (AuNTs) are characterized by unique structural anisotropy and plasmonic properties. The organization of AuNTs into well-defined architecture potentially promises collective properties that are difficult to produce by individual AuNTs. To date, however, the orientation-controlled self-assembly of AuNTs has been achieved with limited success. Here, we describe an effective and straightforward approach to induce directed self-assembly of AuNTs. By taking advantage of the uneven chemical reactivity of AuNT surfaces, we implement regioselective modification of the edges and the top/bottom surfaces with two different double-stranded DNA (dsDNA) sequences. By means of terminal single base pairing/unpairing, controlled assembly of the dsDNA-modified AuNTs evolves in a face-to-face or edge-to-edge manner based on blunt-end stacking interaction on an intentional region of the AuNTs, along with entropic repulsion by unpaired terminal nucleobases on the other region. This approach could be useful for achieving directed self-assembly of other anisotropic nanoparticles.

| S-EPMC6523274 | biostudies-literature

Face-to-Face Assembly of Ag Nanoplates on Filter Papers for Pesticide Detection by Surface-Enhanced Raman Spectroscopy.

Project description:Surface-enhanced Raman spectroscopy (SERS) technology has been regarded as a most efficient and sensitive strategy for the detection of pollutants at ultra-low concentrations. Fabrication of SERS substrates is of key importance in obtaining the homogeneous and sensitive SERS signals. Cellulose filter papers loaded with plasmonic metal NPs are well known as cost-effective and efficient paper-based SERS substrates. In this manuscript, face-to-face assembly of silver nanoplates via solvent-evaporation strategies on the cellulose filter papers has been developed for the SERS substrates. Furthermore, these developed paper-based SERS substrates are utilized for the ultra-sensitive detection of the rhodamine 6G dye and thiram pesticides. Our theoretical studies reveal the creation of high density hotspots, with a huge localized and enhanced electromagnetic field, near the corners of the assembled structures, which justifies the ultrasensitive SERS signal in the fabricated paper-based SERS platform. This work provides an excellent paper-based SERS substrate for practical applications, and one which can also be beneficial to human health and environmental safety.

| S-EPMC9104380 | biostudies-literature

Exploring the Control in Antibacterial Activity of Silver Triangular Nanoplates by Surface Coating Modulation.

Project description:In the present work, the synthesis and characterization of silver triangular nanoplates (AgNTs) and their silica coating composites are reported. Engineering control on the surface coating has demonstrated the possibility to modulate the antibacterial effect. Several AgNT-coated nanomaterials, such as PVP (Polyvinylpyrrolidone) and MHA (16-mercaptohexadecanoic acid) as a stable organic coating system as well as uniform silica coating (≈5 nm) of AgNTs, have been prepared and fully characterized. The antibacterial properties of the systems reported, organic (MHA) and inorganic (amine and carboxylic terminated SiO2) coating nanocomposites, have been tested on Gram-positive and Gram-negative bacteria strains. We observed that the AgNTs' organic coating improved antimicrobial properties when compared to other spherical silver colloids found in the literature. We have also found that thick inorganic silica coating decreases the antimicrobial effect, but does not cancel it. In addition, the effect of surface charge in AgNTs@Si seems to play a crucial role toward S. aureus ATCC 25923 bacteria, obtaining MIC/MBC values compared to the AgNTs with an organic coating.

| S-EPMC6370693 | biostudies-literature

Project description:In this data paper we share the absorption spectrum of Ag NP ablated in pure water and in presence of trisodium citrate (TSC). We also share the full emission spectrum of the irradiation lamp used for the reshaping process described in the related research paper. The data is related to the research article "Plasmon Sensing and enhancement of laser prepared silver colloids" [1].

| S-EPMC6660549 | biostudies-literature

Rapid Detection of Malathion, Phoxim and Thiram on Orange Surfaces Using Ag Nanoparticle Modified PDMS as Surface-Enhanced Raman Spectroscopy Substrate.

Project description:Malathion, phoxim, and thiram are organophosphates and organosulfur pesticides widely used in agricultural products. The residues of these pesticides present a direct threat to human health. Rapid and on-site detection is critical for minimizing such risks. In this work, a simple approach was introduced using a flexible surface-enhanced Raman spectroscopy (SERS) substrate. The prepared Ag nanoparticles-polydimethylsiloxane (AgNPs-PDMS) substrate showed high SERS activity, good precision (relative standard deviation = 5.33%), and stability (30 days) after optimization. For target pesticides, the linear relationship between characteristic SERS bands and concentrations were achieved in the range of 10~1000, 100~5000, and 50~5000 μg L-1 with LODs down to 3.62, 41.46, and 15.69 μg L-1 for thiram, malathion, and phoxim, respectively. Moreover, SERS spectra of mixed samples indicated that three pesticides can be identified simultaneously, with recovery rates between 96.5 ± 3.3% and 118.9 ± 2.4%, thus providing an ideal platform for detecting more than one target. Pesticide residues on orange surfaces can be simply determined through swabbing with the flexible substrate before acquiring the SERS signal. This study demonstrated that the prepared substrate can be used for the rapid detection of pesticides on real samples. Overall, this method greatly simplified the pre-treatment procedure, thus serving as a promising analytical tool for rapid and nondestructive screening of malathion, phoxim, and thiram on various agricultural products.

| S-EPMC9689543 | biostudies-literature

Highly Sensitive Homogeneous Immunoassays Based on Construction of Silver Triangular Nanoplates-Quantum Dots FRET System.

Project description:With growing concerns about health issues worldwide, elegant sensors with high sensitivity and specificity for virus/antigens (Ag) detection are urgent to be developed. Homogeneous immunoassays (HIA) are an important technique with the advantages of small sample volumes requirement and pretreatment-free process. HIA are becoming more favorable for the medical diagnosis and disease surveillance than heterogeneous immunoassays. An important subset of HIA relies on the effect of fluorescence resonance energy transfer (FRET) via a donor-acceptor (D-A) platform, e.g., quantum dots (QDs) donor based FRET system. Being an excellent plasmonic material, silver triangular nanoplates (STNPs) have unique advantages in displaying surface plasmon resonance in the visible to near infrared spectral region, which make them a better acceptor for pairing with QDs in a FRET-based sensing system. However, the reported STNPs generally exhibited broad size distributions, which would greatly restrict their application as HIA acceptor for high detection sensitivity and specificity purpose. In this work, uniform STNPs and red-emitting QDs are firstly applied to construct FRET nanoplatform in the advanced HIA and further be exploited for analyzing virus Ag. The uniform STNPs/QDs nanoplatform based medical sensor provides a straightforward and highly sensitive method for Ag analysis in homogeneous form.

| S-EPMC4873782 | biostudies-literature

Flexible, high-performance and facile PVA/cellulose/Ag SERS chips for in-situ and rapid detection of thiram pesticide in apple juice.

Project description:Flexible surface-enhanced Raman scattering (SERS) sensors have gained significant attention for their practical applications in detecting chemical and biological molecules. However, the fabrication of flexible SERS chips is often complex and requires advanced techniques. In this study, we present a simple and rapid method to design a flexible SERS chip based on polyvinyl alcohol (PVA), cellulose, and silver nanoparticles (AgNPs) using mechanical stirring and drying methods. Benefiting from the abundant hydroxide groups on cellulose, AgNPs easily adhere and distribute evenly on the cellulose surface. The combination of PVA and cellulose forms a bendable film-like SERS chip. This chip allows convenient immersion in liquid analyte samples. We demonstrate its effectiveness by using it to detect the thiram pesticide in apple juice using the "dip and dry" method, achieving an outstanding detection limit of 1.01 × 10-8 M. The Raman signals on the SERS chips exhibit high repeatability and reproducibility, with relative standard deviation values below 10%. These findings show that the flexible PVA/cellulose/Ag SERS chips is a strong candidate for real-world analysis.

| S-EPMC10559351 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data