Ontology highlight
ABSTRACT:
SUBMITTER: Xu H
PROVIDER: S-EPMC9305517 | biostudies-literature | 2022 Feb
REPOSITORIES: biostudies-literature
Xu Huihui H Weetman Catherine C Hanusch Franziska F Inoue Shigeyoshi S
Chemistry (Weinheim an der Bergstrasse, Germany) 20211221 8
Despite the notable progress in aluminium chalcogenides, their sulfur congeners have rarely been isolated under mild conditions owing to limited synthetic precursors and methods. Herein, facile isolation of diverse molecular aluminium sulfides is achievable, by the reaction of N-heterocyclic carbene-stabilized terphenyl dihydridoaluminium (1) with various thiation reagents. Different to the known dihydridoaluminium 1<sup>Tipp</sup> , 1 features balanced stability and reactivity at the Al center. ...[more]