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Enhanced Photocatalytic Hydrogen Evolution from Water Splitting on Ta₂O₅/SrZrO₃ Heterostructures Decorated with Cu_xO/RuO₂ Cocatalysts.

ABSTRACT: Photocatalytic H₂ generation by water splitting is a promising alternative for producing renewable fuels. This work synthesized a new type of Ta₂O₅/SrZrO₃ heterostructure with Ru and Cu (RuO₂/Cu_xO/Ta₂O₅/SrZrO₃) using solid-state chemistry methods to achieve a high H₂ production of 5164 μmol g^-1 h^-1 under simulated solar light, 39 times higher than that produced using SrZrO₃. The heterostructure performance is compared with other Ta₂O₅/SrZrO₃ heterostructure compositions loaded with RuO₂, Cu_xO, or Pt. Cu_xO is used to showcase the usage of less costly cocatalysts to produce H₂. The photocatalytic activity toward H₂ by the RuO₂/Cu_xO/Ta₂O₅/SrZrO₃ heterostructure remains the highest, followed by RuO₂/Ta₂O₅/SrZrO₃ > Cu_xO/Ta₂O₅/SrZrO₃ > Pt/Ta₂O₅/SrZrO₃ > Ta₂O₅/SrZrO₃ > SrZrO₃. Band gap tunability and high optical absorbance in the visible region are more prominent for the heterostructures containing cocatalysts (RuO₂ or Cu_xO) and are even higher for the binary catalyst (RuO₂/Cu_xO). The presence of the binary catalyst is observed to impact the charge carrier transport in Ta₂O₅/SrZrO₃, improving the solar to hydrogen conversion efficiency. The results represent a valuable contribution to the design of SrZrO₃-based heterostructures for photocatalytic H₂ production by solar water splitting.

SUBMITTER: Huerta-Flores AM

PROVIDER: S-EPMC9305716 | biostudies-literature |

REPOSITORIES: biostudies-literature

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