Ontology highlight
ABSTRACT:
SUBMITTER: Buday P
PROVIDER: S-EPMC9313588 | biostudies-literature | 2022 May
REPOSITORIES: biostudies-literature
Buday Philipp P Kasahara Chizuru C Hofmeister Elisabeth E Kowalczyk Daniel D Farh Micheal K MK Riediger Saskia S Schulz Martin M Wächtler Maria M Furukawa Shunsuke S Saito Masaichi M Ziegenbalg Dirk D Gräfe Stefanie S Bäuerle Peter P Kupfer Stephan S Kupfer Stephan S Dietzek-Ivanšić Benjamin B Weigand Wolfgang W
Angewandte Chemie (International ed. in English) 20220323 20
Inspired by the active center of the natural [FeFe] hydrogenases, we designed a compact and precious metal-free photosensitizer-catalyst dyad (PS-CAT) for photocatalytic hydrogen evolution under visible light irradiation. PS-CAT represents a prototype dyad comprising π-conjugated oligothiophenes as light absorbers. PS-CAT and its interaction with the sacrificial donor 1,3-dimethyl-2-phenylbenzimidazoline were studied by steady-state and time-resolved spectroscopy coupled with electrochemical tec ...[more]