Iron-Catalyzed Oxidative C-O and C-N Coupling Reactions Using Air as Sole Oxidant.
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ABSTRACT: We describe the oxygenation of tertiary arylamines, and the amination of tertiary arylamines and phenols. The key step of these coupling reactions is an iron-catalyzed oxidative C-O or C-N bond formation which generally provides the corresponding products in high yields and with excellent regioselectivity. The transformations are accomplished using hexadecafluorophthalocyanine-iron(II) (FePcF16 ) as catalyst in the presence of an acid or a base additive and require only ambient air as sole oxidant.
SUBMITTER: Purtsas A
PROVIDER: S-EPMC9314016 | biostudies-literature |
REPOSITORIES: biostudies-literature
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