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Pd(II)-catalyzed C-H iodination using molecular I2 as the sole oxidant.

ABSTRACT: Pd-catalyzed ortho-C-H iodination directed by a weakly coordinating amide auxiliary using I2 as the sole oxidant was developed. This reaction is compatible with a wide range of heterocycles including pyridines, imidazoles, oxazoles, thiazoles, isoxazoles, and pyrazoles.

SUBMITTER: Wang XC 

PROVIDER: S-EPMC3762701 | biostudies-literature | 2013 Jul

REPOSITORIES: biostudies-literature

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Pd(II)-catalyzed C-H iodination using molecular I2 as the sole oxidant.

Wang Xiao-Chen XC   Hu Yi Y   Bonacorsi Samuel S   Hong Yang Y   Burrell Richard R   Yu Jin-Quan JQ  

Journal of the American Chemical Society 20130709 28

Pd-catalyzed ortho-C-H iodination directed by a weakly coordinating amide auxiliary using I2 as the sole oxidant was developed. This reaction is compatible with a wide range of heterocycles including pyridines, imidazoles, oxazoles, thiazoles, isoxazoles, and pyrazoles. ...[more]

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