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Fabrication and Investigation of PE-SiO₂@PZS Composite Separator for Lithium-Ion Batteries.

ABSTRACT: Commercial polyolefin separators exhibit problems including shrinkage under high temperatures and poor electrolyte wettability and uptake, resulting in low ionic conductivity and safety problems. In this work, core-shell silica-polyphosphazene nanoparticles (SiO₂@PZS) with different PZS layer thicknesses were synthesized and coated onto both sides of polyethylene (PE) microporous membranes to prepare composite membranes. Compared to pure silica-coated membranes and PE membranes, the PE-SiO₂@PZS composite membrane had higher ionic conductivity. With the increase in the SiO₂@PZS shell thickness, the electrolyte uptake, ionic conductivity and discharge capacity gradually increased. The discharge capacity of the PE-SiO₂@PZS composite membrane at 8 C rate was 129 mAh/g, which was higher than the values of 107 mAh/g for the PE-SiO₂ composite membrane and 104 mAh/g for the PE membrane.

SUBMITTER: Xu L

PROVIDER: S-EPMC9322529 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature

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Fabrication and Investigation of PE-SiO2@PZS Composite Separator for Lithium-Ion Batteries.

Xu Liguo L Chen Yanwu Y Liu Peijiang P Zhan Jianghua J

Materials (Basel, Switzerland) 20220713 14

Commercial polyolefin separators exhibit problems including shrinkage under high temperatures and poor electrolyte wettability and uptake, resulting in low ionic conductivity and safety problems. In this work, core-shell silica-polyphosphazene nanoparticles (SiO2@PZS) with different PZS layer thicknesses were synthesized and coated onto both sides of polyethylene (PE) microporous membranes to prepare composite membranes. Compared to pure silica-coated membranes and PE membranes, the P ...[more]

PMID: 35888341

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