Browse
Submit Data
Databases
API
Help

Dataset Information

26 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

MoS2-Decorated Graphene@porous Carbon Nanofiber Anodes via Centrifugal Spinning

ABSTRACT: Sodium-ion batteries (SIBs) are promising alternatives to lithium-ion batteries as green energy storage devices because of their similar working principles and the abundance of low-cost sodium resources. Nanostructured carbon materials are attracting great interest as high-performance anodes for SIBs. Herein, a simple and fast technique to prepare carbon nanofibers (CNFs) is presented, and the effects of carbonization conditions on the morphology and electrochemical properties of CNF anodes in Li- and Na-ion batteries are investigated. Porous CNFs containing graphene were fabricated via centrifugal spinning, and MoS2 were decorated on graphene-included porous CNFs via hydrothermal synthesis. The effect of MoS2 on the morphology and the electrode performance was examined in detail. The results showed that the combination of centrifugal spinning, hydrothermal synthesis, and heat treatment is an efficient way to fabricate high-performance electrodes for rechargeable batteries. Furthermore, CNFs fabricated at a carbonization temperature of 800 °C delivered the highest capacity, and the addition of MoS2 improved the reversible capacity up to 860 mAh/g and 455 mAh/g for Li- and Na-ion batteries, respectively. A specific capacity of over 380 mAh/g was observed even at a high current density of 1 A/g. Centrifugal spinning and hydrothermal synthesis allowed for the fabrication of high-performance electrodes for sodium ion batteries.

SUBMITTER: Abdolrazzaghian E

PROVIDER: S-EPMC9323995 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Flexible MnO nanoparticle-anchored N-doped porous carbon nanofiber interlayers for superior performance lithium metal anodes.

Project description:The mounting requirements for electric apparatus and vehicles stimulate the rapid progress of energy storage systems. Lithium (Li) metal is regarded as one of the most prospective anodes for high-performance cells. However, the uneven dendrite growth is one of the primary conundrums that hampers the use of the Li metal anode in rechargeable Li batteries. Achieving even Li deposition is crucial to solve this concern. In this study, a stable interlayer based on electrospun flexible MnO nanoparticle/nitrogen (N)-doped (polyimide) PI-based porous carbon nanofiber (MnO-PCNF) films was effectively prepared via electrospinning and in situ growth of MnO to reduce the growth of Li dendrites. It is revealed that the attraction of implanted MnO towards Li, the lithiophilic nature of N dopants and the capillary force of porous architectures are beneficial to the preeminent Li wettability of the MnO-PCNF interlayer. Furthermore, the wettable, stable and conductive structure of the MnO-PCNF interlayer can be retained well, offering rapid charge transfer to Li redox reactions, reduced local current density during the cycling process and homogeneous distribution of deposited Li. Consequently, anodes with MnO-PCNF interlayers can relieve the volume change and inhibit the growth of Li dendrites, demonstrating a remarkable lifetime for lithium metal cells at high current.

| S-EPMC9419476 | biostudies-literature

MoS2-Decorated/Integrated Carbon Fiber: Phase Engineering Well-Regulated Microwave Absorber.

Project description:Phase engineering is an important strategy to modulate the electronic structure of molybdenum disulfide (MoS2). MoS2-based composites are usually used for the electromagnetic wave (EMW) absorber, but the effect of different phases on the EMW absorbing performance, such as 1T and 2H phase, is still not studied. In this work, micro-1T/2H MoS2 is achieved via a facile one-step hydrothermal route, in which the 1T phase is induced by the intercalation of guest molecules and ions. The EMW absorption mechanism of single MoS2 is revealed by presenting a comparative study between 1T/2H MoS2 and 2H MoS2. As a result, 1T/2H MoS2 with the matrix loading of 15% exhibits excellent microwave absorption property than 2H MoS2. Furthermore, taking the advantage of 1T/2H MoS2, a flexible EMW absorbers that ultrathin 1T/2H MoS2 grown on the carbon fiber also performs outstanding performance only with the matrix loading of 5%. This work offers necessary reference to improve microwave absorption performance by phase engineering and design a new type of flexible electromagnetic wave absorption material to apply for the portable microwave absorption electronic devices.

| S-EPMC8079512 | biostudies-literature

TiO2/Porous Carbon Composite-Decorated Separators for Lithium/Sulfur Battery.

Project description:The practical application of lithium/sulfur (Li/S) batteries is hindered by the migration of soluble polysulfides (Li2Sn, 4???n???8) from cathode to anode, leading to poor electrochemical stability of the cell. To address this issue, in the present study, a TiO2/porous carbon (TiO2/PC) composite-coated Celgard 2400 separator was successfully fabricated and used as a polysulfide barrier for the Li/S battery. In TiO2/PC, the highly conductive PC with three-dimensional ordered porous structure physically constrains polysulfides and at the same time serves as an additional upper current collector. On the other hand, the TiO2 on the surface of PC chemically adsorbed polysulfides during the charge/discharge process. Due to the physical and chemical adsorption properties of TiO2/PC composite coating layer, an initial discharge capacity of 926 mAh g-1 at 0.1 C and a low fading rate (75% retention after 150?cycles) were achieved. Moreover, in the rate capability test, the discharge capacity for the TiO2/PC-modified Li/S battery was recovered to 728 mAh g-1 at 0.1 C after high-rate cycling and remained ~?88% of the initial reversible capacity.

| S-EPMC6538749 | biostudies-literature

High-Performance Flexible Energy Storage Devices Based on Graphene Decorated with Flower-Shaped MoS2 Heterostructures.

Project description:MoS2, owing to its advantages of having a sheet-like structure, high electrical conductivity, and benign environmental nature, has emerged as a candidate of choice for electrodes of next-generation supercapacitors. Its widespread use is offset, however, by its low energy density and poor durability. In this study, to overcome these limitations, flower-shaped MoS2/graphene heterostructures have been deployed as electrode materials on flexible substrates. Three-electrode measurements yielded an exceptional capacitance of 853 F g-1 at 1.0 A g-1, while device measurements on an asymmetric supercapacitor yielded 208 F g-1 at 0.5 A g-1 and long-term cyclic durability. Nearly 86.5% of the electrochemical capacitance was retained after 10,000 cycles at 0.5 A g-1. Moreover, a remarkable energy density of 65 Wh kg-1 at a power density of 0.33 kW kg-1 was obtained. Our MoS2/Gr heterostructure composites have great potential for the development of advanced energy storage devices.

| S-EPMC9967960 | biostudies-literature

Facile and Scalable Fabrication of Porous Polystyrene Fibers for Oil Removal by Centrifugal Spinning.

Project description:The demand for an efficient oil sorbent with high sorption capacity, low cost, scalable fabrication, and high selectivity for the cleanup of spreading oil on water is increasingly urgent due to the frequent occurrence of oil spill accidents in seawater all over the world. In this study, porous polystyrene (PS) fibers with high hydrophobicity and superoleophilicity were directly fabricated by a centrifugal spinning method (CS). The effect of solvents, tetrahydrofuran (THF), and dimethylformamide (DMF) on the morphology and porous structure of the polystyrene fibers was evaluated by using scanning electron microscopy and nitrogen adsorption-desorption experiments. The formation mechanism for the porous structure on the fibers was also evaluated. The oil sorption capacities of the PS fibers for silicon oil, pump oil, and vegetable oil were investigated. The highest oil sorption capacity was found in PS fibers fabricated from PS solution with a THF/DMF weight ratio of 1/3, which exhibited the highest specific surface area, pore volume, and porosity. The high productivity and highly porous structure of PS fibers indicate that CS is a promising method to fabricate porous fibers for the cleanup of oil spills.

| S-EPMC6777073 | biostudies-literature

Synergistically Enhanced Electrocatalytic Performance of an N-Doped Graphene Quantum Dot-Decorated 3D MoS2-Graphene Nanohybrid for Oxygen Reduction Reaction.

Project description:Nitrogen-doped graphene quantum dots (N-GQDs) were decorated on a three-dimensional (3D) MoS2-reduced graphene oxide (rGO) framework via a facile hydrothermal method. The distribution of N-GQDs on the 3D MoS2-rGO framework was confirmed using X-ray photoelectron spectroscopy, energy dispersive X-ray elemental mapping, and high-resolution transmission electron microscopy techniques. The resultant 3D nanohybrid was successfully demonstrated as an efficient electrocatalyst toward the oxygen reduction reaction (ORR) under alkaline conditions. The chemical interaction between the electroactive N-GQDs and MoS2-rGO and the increased surface area and pore size of the N-GQDs/MoS2-rGO nanohybrid synergistically improved the ORR onset potential to +0.81 V vs reversible hydrogen electrode (RHE). Moreover, the N-GQDs/MoS2-rGO nanohybrid showed better ORR stability for up to 3000 cycles with negligible deviation in the half-wave potential (E 1/2). Most importantly, the N-GQDs/MoS2-rGO nanohybrid exhibited a superior methanol tolerance ability even under a high concentration of methanol (3.0 M) in alkaline medium. Hence, the development of a low-cost metal-free graphene quantum dot-based 3D nanohybrid with high methanol tolerance may open up a novel strategy to design selective cathode electrocatalysts for direct methanol fuel cell applications.

| S-EPMC6640782 | biostudies-literature

Plasmonic Ag-Decorated Few-Layer MoS2 Nanosheets Vertically Grown on Graphene for Efficient Photoelectrochemical Water Splitting.

Project description:A controllable approach that combines surface plasmon resonance and two-dimensional (2D) graphene/MoS2 heterojunction has not been implemented despite its potential for efficient photoelectrochemical (PEC) water splitting. In this study, plasmonic Ag-decorated 2D MoS2 nanosheets were vertically grown on graphene substrates in a practical large-scale manner through metalorganic chemical vapor deposition of MoS2 and thermal evaporation of Ag. The plasmonic Ag-decorated MoS2 nanosheets on graphene yielded up to 10 times higher photo-to-dark current ratio than MoS2 nanosheets on indium tin oxide. The significantly enhanced PEC activity could be attributed to the synergetic effects of SPR and favorable graphene/2D MoS2 heterojunction. Plasmonic Ag nanoparticles not only increased visible-light and near-infrared absorption of 2D MoS2, but also induced highly amplified local electric field intensity in 2D MoS2. In addition, the vertically aligned 2D MoS2 on graphene acted as a desirable heterostructure for efficient separation and transportation of photo-generated carriers. This study provides a promising path for exploiting the full potential of 2D MoS2 for practical large-scale and efficient PEC water-splitting applications.

| S-EPMC7770824 | biostudies-literature

Electrochemical performance of myoglobin based on TiO2-doped carbon nanofiber decorated electrode and its applications in biosensing.

Project description:A new biosensing strategy based on a TiO2-doped carbon nanofiber (CNF) composite modified electrode was developed. TiO2@CNF was prepared by electrospinning with further carbonization, before being characterized by various methods and used for electrode modification on the surface of carbon ionic liquid electrode (CILE). Myoglobin (Mb) was further immobilized on the modified electrode surface. The results of ultraviolet-visible (UV-vis) and Fourier transform infrared (FT-IR) spectroscopy showed that Mb maintained its native structure without denaturation in the composite film. Direct electron transfer and the electrocatalytic properties of Mb on the electrode surface were further investigated. A pair of quasi-reversible redox peaks appeared on the cyclic voltammogram, indicating that direct electrochemistry of Mb was realized in the nanocomposite film. This could be attributed to the specific properties of TiO2@CNF nanocomposite, including a large surface-to-volume ratio, good biocompatibility and high conductivity. Nafion/Mb/TiO2@CNF/CILE exhibited an excellent electrochemical catalytic ability in the reduction of trichloroacetic acid, NaNO2 and H2O2. All results demonstrated potential applications of TiO2@CNF in third-generation electrochemical biosensors.

| S-EPMC9060622 | biostudies-literature

Dataset of optical and electronic properties for MoS2-graphene vertical heterostructures and MoS2-graphene-Au heterointerfaces.

Project description:The computational and experimental data presented in this paper refer to the research article "First-Principles Calculations Integrated with Experimental Optical and Electronic Properties for MoS2-graphene Heterostructures and MoS2-graphene-Au Heterointerfaces". The computational data includes structural information, electronic and optical properties, and data to calculate the work functions for various molybdenum disulfide and graphene heterostructures and their heterointerfaces with gold. The optical properties calculations include the frequency-dependent dielectric function, the refractive index, the reflectivity, the extinction coefficient, and the energy loss function. These properties were calculated using the independent particle approximation (IPA). As for the experimental optoelectronic properties, we measured photoluminescence spectra (optical), Raman spectra (vibrational), work function (surface electronic property), and local photoconductivity (semiconducting behavior) of graphene-MoS2 heterointerfaces in addition to individual graphene and MoS2 layers on gold. The variation in the exciton bands, the Raman bands, and in the average work function elucidated the semiconducting n-p junction behavior.

| S-EPMC10439301 | biostudies-literature

SiO2 Fibers by Centrifugal Spinning with Excellent Textural Properties and Water Adsorption Performance.

Project description:Facile and innovative route for large-scale synthesis of SiO2 fibers with excellent textural properties and H2O adsorption performance is presented. At first, a three-dimensional network of SiO2 precursor fibers was produced from tailored spun solutions (without any toxic elements and surfactants) by centrifugal spinning, which is a very modern fiber-synthesis technique, with numerous advantages over electrospinning. Upon thermal annealing of the precursor fibers, mesoporous amorphous SiO2 fibers with an ultrahigh surface area of up to 824 m2/g and pore size distribution in the range of 2-10 nm were produced. Owing to the high number of OH groups available on the surface, the produced SiO2 fibers showed significantly better performance in H2O adsorption compared to that of the reference silicagel.

| S-EPMC6641703 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data