Ontology highlight
ABSTRACT:
SUBMITTER: Zhang X
PROVIDER: S-EPMC9400893 | biostudies-literature | 2022 Jul
REPOSITORIES: biostudies-literature
Chemistry (Weinheim an der Bergstrasse, Germany) 20220613 42
Herein, the copper-catalyzed borylation of readily available acyl chlorides with bis(pinacolato)diboron, (B<sub>2</sub> pin<sub>2</sub> ) or bis(neopentane glycolato)diboron (B<sub>2</sub> neop<sub>2</sub> ) is reported, which provides stable potassium acyltrifluoroborates (KATs) in good yields from the acylboronate esters. A variety of functional groups are tolerated under the mild reaction conditions (room temperature) and substrates containing different carbon-skeletons, such as aryl, heteroa ...[more]