Ontology highlight
ABSTRACT:
SUBMITTER: Shimoni R
PROVIDER: S-EPMC9401588 | biostudies-literature | 2022 Aug
REPOSITORIES: biostudies-literature
Shimoni Ran R Shi Zhuocheng Z Binyamin Shahar S Yang Yang Y Liberman Itamar I Ifraemov Raya R Mukhopadhyay Subhabrata S Zhang Liwu L Hod Idan I
Angewandte Chemie (International ed. in English) 20220628 32
Metal-organic frameworks (MOFs) are promising platforms for heterogeneous tethering of molecular CO<sub>2</sub> reduction electrocatalysts. Yet, to further understand electrocatalytic MOF systems, one also needs to consider their capability to fine-tune the immediate chemical environment of the active site, and thus affect its overall catalytic operation. Here, we show that electrostatic secondary-sphere functionalities enable substantial improvement of CO<sub>2</sub> -to-CO conversion activity ...[more]