Dataset Information

Ultrafine platinum nanoparticles supported on N,S-codoped porous carbon nanofibers as efficient multifunctional materials for noticeable oxygen reduction reaction and water splitting performance.

ABSTRACT: The design of highly active, stable and durable platinum-based electrocatalysts towards the oxygen reduction reaction (ORR), oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and hydrogen adsorption has a high and urgent demand in fuel cells, water splitting and hydrogen storage. Herein, ultrafine platinum nanoparticles (Pt NPs) supported on N,S-codoped porous carbon nanofibers (Pt-N,S-pCNFs) hybrids were prepared through the electrospinning method coupled with hydrothermal and carbonation processes. The ultrafine Pt NPs are sufficiently dispersed and loaded on pCNFs and codoped with N and S, which can improve oxygen adsorption, afford more active sites, and greatly enhance electron mobility. The Pt-N,S-pCNFs hybrid achieves excellent activity and stability for ORR with ∼70 mV positive shift of onset potential compared to the commercial Pt/C-20 wt% electrocatalyst. The long-term catalytic durability with 89.5% current retention after a 10 000 s test indicates its remarkable ORR behavior. Pt-N,S-pCNFs also exhibits excellent HER and OER performance, and can be used as an efficient catalyst for water splitting. In addition, Pt-N,S-pCNFs exhibits an excellent hydrogen storage capacity of 0.76 wt% at 20 °C and 10 MPa. This work provides novel design strategies for the development of multifunctional materials as high-performance ORR catalysts, water splitting electrocatalysts and hydrogen storage materials.

SUBMITTER: Chen X

PROVIDER: S-EPMC9417137 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Ultrafine platinum nanoparticles supported on N,S-codoped porous carbon nanofibers as efficient multifunctional materials for noticeable oxygen reduction reaction and water splitting performance.

Chen Xiaohong X Niu Kai K Xue Zhiyong Z Liu Xundao X Liu Bogu B Zhang Bao B Zeng Hong H Lv Wei W Zhang Yongming Y Wu Ying Y

Nanoscale advances 20220301 6

The design of highly active, stable and durable platinum-based electrocatalysts towards the oxygen reduction reaction (ORR), oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and hydrogen adsorption has a high and urgent demand in fuel cells, water splitting and hydrogen storage. Herein, ultrafine platinum nanoparticles (Pt NPs) supported on N,S-codoped porous carbon nanofibers (Pt-N,S-pCNFs) hybrids were prepared through the electrospinning method coupled with hydrothermal and ...[more]

PMID: 36134368

Similar Datasets

Project description:The quest for efficient and economically accessible cleaner methods to develop sustainable carbon-free energy sources induced a keen interest in the production of hydrogen fuel. This can be achieved via the water-splitting process and by exploiting solar energy. However, the use of adequate photocatalysts is required to reach this goal. Covalent triazine-based frameworks (CTFs) are potential target photocatalysts for water splitting. Both electronic and structural characteristics of CTFs, particularly energy levels, optical band gaps, and porosities are directly relevant to water splitting and can be engineered through chemical design. Porosity can, in principle, be beneficial to water splitting by providing a larger surface area for the catalytic reactions to take place. However, porosity can also affect both charge transport within the photocatalyst and mass transfer of both reactants and products, thus impacting the overall kinetics of the reaction. Here, we focus on the link between chemical design and water (reactant) mass transfer, which plays a key role in the water uptake process and the subsequent hydrogen generation in practice. We use neutron spectroscopy to study the mass transfer of water in two porous CTFs, CTF-CN and CTF-2, that differ in the polarity of their struts. Quasi-elastic neutron scattering is used to quantify the amount of bound water and the translational diffusion of water. Inelastic neutron scattering measurements complement the quasi-elastic neutron scattering study and provide insights into the softness of the CTF structures and the changes in librational degrees of freedom of water in the porous CTFs. We show that two different types of interaction between water and CTFs take place in CTF-CN and CTF-2. CTF-CN exhibits a smaller surface area and lower water uptake due to its softer structure than CTF-2. However, the polar cyano group interacts locally with water leading to a large amount of bound water and a strong rearrangement of the water hydration monolayer, while water diffusion in CTF-2 is principally impacted by microporosity. The current study leads to new insights into the structure-dynamics-property relationship of CTF photocatalysts that pave the road for a better understanding of the guest-host interaction on the basis of water-splitting applications.

Dataset Information

Ultrafine platinum nanoparticles supported on N,S-codoped porous carbon nanofibers as efficient multifunctional materials for noticeable oxygen reduction reaction and water splitting performance.

Publications

Ultrafine platinum nanoparticles supported on N,S-codoped porous carbon nanofibers as efficient multifunctional materials for noticeable oxygen reduction reaction and water splitting performance.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets