Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Dye-sensitized TiO₂ nanotube membranes act as a visible-light switchable diffusion gate.

ABSTRACT: Here we report that both-end open anodic TiO₂ nanotube membranes, after sensitization with a Ru(ii)-based dye, exhibit visible-light switching properties for flow-through the nanotube channels. Under illumination, the gate is in an open state providing ∼four-times faster permeation of small molecules through the membrane compared to a dark state. Switching is reversible with no apparent dye degradation being observed. Gating is possible not only of permeating dye molecules but also of nanoprobes such as polystyrene nanospheres. Supported by quantitative modelling, we attribute the switching mechanism to light-induced changes of the charge distribution at the dye/TiO₂ interface which in turn alters the hydrodynamics within the anodic tube membranes. This demonstrates that these simple dye-sensitized nanotube membranes can be used as an optically addressable flow-through gate in nanofluidics.

SUBMITTER: Hwang I

PROVIDER: S-EPMC9418696 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Dye-sensitized TiO2 nanotube membranes act as a visible-light switchable diffusion gate.

Hwang Imgon I Riboni Francesca F Gongadze Ekaterina E Iglič Aleš A Yoo JeongEun J So Seulgi S Mazare Anca A Schmuki Patrik P

Nanoscale advances 20191111 12

Here we report that both-end open anodic TiO2 nanotube membranes, after sensitization with a Ru(ii)-based dye, exhibit visible-light switching properties for flow-through the nanotube channels. Under illumination, the gate is in an open state providing ∼four-times faster permeation of small molecules through the membrane compared to a dark state. Switching is reversible with no apparent dye degradation being observed. Gating is possible not only of permeating dye molecules but also of ...[more]

PMID: 36133131

Similar Datasets

Au-Embedded and Carbon-Doped Freestanding TiO2 Nanotube Arrays in Dye-Sensitized Solar Cells for Better Energy Conversion Efficiency.

Project description:Dye-sensitized solar cells (DSSCs) are fabricated with freestanding TiO2 nanotube arrays (TNTAs) which are incorporated with Au nanoparticles (NPs) and carbon materials via electrodeposition and chemical vapor deposition (CVD) method to create a plasmonic effect and better electron transport that will enhance their energy conversion efficiency (ECE). The ECE of DSSCs based on the freestanding TNTAs is 5.87%. The ECE of DSSCs, based on the freestanding TNTAs with Au NPs or carbon materials, is 6.57% or 6.59%, respectively, and the final results of DSSCs according to the freestanding TNTAs with Au NPs and carbon materials is increased from 5.87% to 7.24%, which is an enhancement of 23.34% owing to plasmonic effect and better electron transport. Au NPs are incorporated into the channel of freestanding TNTAs and are characterized by CS-corrected-field emission transmission electron microscope (Cs-FE-TEM) and elemental mapping. Carbon materials are also well-incorporated in the channel of freestanding TNTAs and are analyzed by Raman spectroscopy.

| S-EPMC6953097 | biostudies-literature

A dye-sensitized visible light photocatalyst-Bi24O31Cl10.

Project description:The p-block semiconductors are regarded as a new family of visible-light photocatalysts because of their dispersive and anisotropic band structures as well as high chemical stability. The bismuth oxide halides belong to this family and have band structures and dispersion relations that can be engineered by modulating the stoichiometry of the halogen elements. Herein, we have developed a new visible-light photocatalyst Bi24O31Cl10 by band engineering, which shows high dye-sensitized photocatalytic activity. Density functional theory calculations reveal that the p-block elements determine the nature of the dispersive electronic structures and narrow band gap in Bi24O31Cl10. Bi24O31Cl10 exhibits excellent visible-light photocatalytic activity towards the degradation of Rhodamine B, which is promoted by dye sensitization due to compatible energy levels and high electronic mobility. In addition, Bi24O31Cl10 is also a suitable photoanode material for dye-sensitized solar cells and shows power conversion efficiency of 1.5%.

| S-EPMC4260216 | biostudies-literature

Polyaniline-Layered Rutile TiO2 Nanorods as Alternative Photoanode in Dye-Sensitized Solar Cells.

Project description:In this paper, dye-sensitized solar cell (DSSC) performance of the less explored polymorph of TiO2, rutile, has been explored, and its performance has been modified with polyaniline (PANI) wrapping on the surface. For this purpose, highly crystalline rutile nanorods have been synthesized without any growth-directing substrates, employing a hydrothermal treatment. Further, to understand the phase composition and morphology, the synthesized nanorods and PANI-layered nanorods have been characterized through various physicochemical methods. The synthesized rods were implemented as photoanode material for DSSCs which exhibited a photoelectric conversion efficiency (PCE) of 4.28% with a high open-circuit voltage (V OC) of 0.84 V which is highly superior to DSSC with Degussa P25 (PCE = 3.95%) TiO2 nanoparticles. The resultant PCE of the nanorods was further enhanced to 6.23% on in situ deposition of PANI which acts as an electron-transporting layer. Introduction of conducting PANI over the rutile rod was explored as a new concept to improve the performance of photoanode material besides conventional TiCl4 treatment or scattering layer deposition.

| S-EPMC6647995 | biostudies-literature

Impact of Photosensitizing Multilayered Structure on Ruthenium(II)-Dye-Sensitized TiO2-Nanoparticle Photocatalysts.

Project description:To improve the efficiency of photoinduced charge separation on the surface of dye-sensitized TiO2 nanoparticles, we synthesized the Ru(II)-photosensitizer-immobilized, Pt-cocatalyst-loaded TiO2 nanoparticles RuCP 2 @Pt-TiO2, RuCP 2 -Zr-RuP 6 @Pt-TiO2, and RuCP 2 -Zr-RuP 4 -Zr-RuP 6 @Pt-TiO2 (RuCP 2 = [Ru(bpy)2(mpbpy)]2-, RuP 4 = [Ru(bpy)(pbpy)2]6-, RuP 6 = [Ru(pbpy)3]10-, H4mpbpy = 2,2'-bipyridine-4,4'-bis(methanephosphonic acid), and H4pbpy = 2,2'-bipyridine-4,4'-bis(phosphonic acid)) using phosphonate linkers with bridging Zr4+ ions. X-ray fluorescence and ultraviolet-visible absorption spectra revealed that a layered molecular structure composed of Ru(II) photosensitizers and Zr4+ ions (i.e., RuCP 2 -Zr-RuP 6 and RuCP 2 -Zr-RuP 4 -Zr-RuP 6 ) was successfully formed on the surface of Pt-TiO2 nanoparticles, which increased the surface coverage from 0.113 nmol/cm2 for singly layered RuCP 2 @Pt-TiO2 to 0.330 nmol/cm2 for triply layered RuCP 2 -Zr-RuP 4 -Zr-RuP 6 @Pt-TiO2. The photocatalytic H2 evolution activity of the doubly layered RuCP 2 -Zr-RuP 6 @Pt-TiO2 was three times higher than that of the singly layered RuCP 2 @Pt-TiO2, whereas the activity of triply layered RuCP 2 -Zr-RuP 4 -Zr-RuP 6 @Pt-TiO2 was less than half of that for RuCP 2 @Pt-TiO2. The photosensitizing efficiencies of these Ru(II)-photosensitizer-immobilized nanoparticles for the O2 evolution reaction catalyzed by the Co(II)-containing Prussian blue analogue [CoII(H2O)2]1.31[{CoIII(CN)6}0.63{PtII(CN)4}0.37] decreased as the number of Ru(II)-photosensitizing layers increased. Thus, crucial aspects of the energy- and electron-transfer mechanism for the photocatalytic H2 and O2 evolution reactions involve not only the Ru(II)-complex-TiO2 interface but also the multilayered structure of the Ru(II)-photosensitizers on the Pt-TiO2 surface.

| S-EPMC6641294 | biostudies-literature

Enhanced Efficiency in Dye-Sensitized Solar Cells by Electron Transport and Light Scattering on Freestanding TiO₂ Nanotube Arrays.

Project description:Dye-sensitized solar cells (DSSCs) were fabricated with closed- or open-ended freestanding TiO₂ nanotube arrays as photoelectrodes that were decorated with carbon materials and large TiO₂ nanoparticles (NPs) to enhance energy conversion efficiency. The energy conversion efficiency of DSSCs based on open-ended freestanding TiO₂ nanotube arrays increased from 4.47% to 5.39%, compared to the DSSCs based on closed-ended freestanding TiO₂ nanotube arrays. In DSSCs based on the open-ended freestanding TiO₂ nanotube arrays, the energy conversion efficiency with carbon materials increased from 5.39% to 6.19% due to better electron transport, and that with a scattering layer from 5.39% to 6.24% due to more light harvesting compared to the DSSCs without carbon materials or scattering layer. Moreover, the energy conversion efficiency of DSSCs based on the open-ended freestanding TiO₂ nanotube arrays with both carbon materials and scattering layer increased from 5.39% to 6.98%, which is an enhancement of 29.50%. In DSSCs based on the TiO₂ nanotube arrays, the carbon materials can improve electron transport by π-π conjugation, and the large TiO₂ NPs can enhance the capacity to light-harvest by scattering.

| S-EPMC5666510 | biostudies-literature

Visible-light-driven CO2 reduction on dye-sensitized NiO photocathodes decorated with palladium nanoparticles.

Project description:The thin-layer-stacked dye-sensitized NiO photocathodes decorated with palladium nanoparticles (nPd) can be used for the visible-light-driven selective reduction of CO2, mostly to CO, at potentials starting as low as 0 V vs. RHE (compared to -0.6 V in the dark for electrocatalysis). The photosensitization of NiO by the organic dye P1, with a surface coverage of 1.5 × 10-8 mol cm-2, allows the hybrid material to absorb light in the 400-650 nm range. In addition, it improves the stability and the catalytic activity of the final material decorated with palladium nanoparticles (nPd). The resulting multi-layered-type photocathode operates according to the electron-transfer-cascade mechanism. On the one hand, the photosensitizer P1 plays a central role as it generates excited-state electrons and transfers them to nPd, thus producing the catalytically active hydride material PdH x . On the other hand, the dispersed nPd, absorb/adsorb hydrogen and accumulate electrons, thus easing the reductive electrocatalysis process by further driving the separation of charges at the photoelectrochemical interface. Surface analysis, morphology, and roughness have been assessed using SEM, EDS, and AFM imaging. Both conventional electrochemical and photoelectrochemical experiments have been performed to confirm the catalytic activity of hybrid photocathodes toward the CO2 reduction. The recorded cathodic photocurrents have been found to be dependent on the loading of Pd nanoparticles. A sufficient amount of loaded catalyst facilitates the electron transfer cascade, making the amount of dye grafted at the surface of the electrode the limiting parameter in catalysis. The formation of CO as the main reaction product is postulated, though the formation of traces of other small organic molecules (e.g. methanol) cannot be excluded.

| S-EPMC9056418 | biostudies-literature

Photovoltaic Effects of Dye-Sensitized Solar Cells Using Double-Layered TiO2 Photoelectrodes and Pyrazine-Based Photosensitizers.

Project description:In this study, to obtain high performances of the dye-sensitized solar cells using the optimal TiO2 photoelectrode for the synthesized pyrazine-based organic photosensitizers, three types of TiO2 photoelectrodes were fabricated and evaluated for comparison. The double-layered nanoporous TiO2 photoelectrode (SPD type) consisted of a dispersed TiO2 layer and a transparent TiO2 layer. The single-layered nanoporous TiO2 photoelectrodes (D type and SP type) consisted of a dispersed TiO2 layer and a transparent TiO2 layer, respectively. The surface area, pore volume, and crystalline structures of the three types of TiO2 photoelectrodes were analyzed by Brunauer-Emmett-Teller method, field-emission scanning electron microscopy, and X-ray diffractometry to confirm their crystallinity and surface morphology. The structures of the three types of TiO2 photoelectrode-adsorbed organic sensitizers were investigated using X-ray photoelectron spectroscopy. The photovoltaic performances of DSSC devices using three organic photosensitizers adsorbed onto the three types of TiO2 photoelectrodes were investigated under a light intensity of 100 mW/cm2 at AM 1.5. The DSSC device using double-layered SPD type TiO2 photoelectrodes displayed 1.31∼2.64% efficiency, compared to single-layered SP type TiO2 photoelectrodes (1.31∼2.50%) and D type TiO2 photoelectrodes (0.90∼1.54%), using organic photosensitizers. The DSSC device using the SPD type TiO2 photoelectrode and trifluoromethylbenzopyrazine (TPPF) as a photosensitizer showed the highest performances: J sc of 5.69 mA/cm2, V oc of 0.69 V, FF of 0.67, and efficiency of 2.64%. The relationship between photovoltaic effects and interfacial resistance characteristics of DSSCs using the three organic photosensitizers adsorbed onto the three types of TiO2 photoelectrodes could be interpreted from interfacial resistances according to frequency through impedance analysis.

| S-EPMC10134224 | biostudies-literature

MOF-derived Co2+-doped TiO2 nanoparticles as photoanodes for dye-sensitized solar cells.

Project description:Facile synthesis and application of nano-sized semiconductor metal oxides for optoelectronic devices have always affected fabrication challenges since it involves multi-step synthesis processes. In this regard, semiconductor oxides derived directly from metal-organic frameworks (MOFs) routes have gained a great deal of scientific interest owing to their high specific surface area, regular and tunable pore structures. Exploring the application potential of these MOF-derived semiconductor oxides systems for clean energy conversion and storage devices is currently a hot topic of research. In this study, titanium-based MIL-125(Ti) MOFs were used as a precursor to synthesize cobalt-doped TiO2-based dye-sensitized solar cells (DSSCs) for the first time. The thermal decomposition of the MOF precursor under an air atmosphere at 400 °C resulted in mesoporous anatase-type TiO2 nanoparticles (NPs) of uniform morphology, large surface area with narrow pore distribution. The Co2+ doping in TiO2 leads to enhanced light absorption in the visible region. When used as photoanode in DSSCs, a good power conversion efficiency (PCE) of 6.86% with good photocurrent density (Jsc) of 13.96 mA cm-2 was obtained with the lowest recombination resistance and the longest electron lifetime, which is better than the performance of the pristine TiO2-based photoanode.

| S-EPMC8358052 | biostudies-literature

Au nanoparticle-decorated TiO2 hollow fibers with enhanced visible-light photocatalytic activity toward dye degradation.

Project description:TiO2 hollow fibers (THF) were prepared by a template method using kapok as a biotemplate and subsequently decorated by plasmonic Au nanoparticles using a solution plasma process. The THF exhibited an anatase phase and a hollow structure with a mesoporous wall. Au nanoparticles with a diameter of about 5-10 nm were uniformly distributed on the THF surface. Au nanoparticles-decorated TiO2 hollow fibers (Au/THF) have enhanced photocatalytic activity toward methylene blue degradation under visible light-emitting diode (Vis-LED) as compared to pristine THF and P25. This could be attributed to combined effects including effective light-harvesting by a hollow structure, large surface area due to a mesoporous wall of THF, and visible-light absorption and efficient charge separation induced by Au nanoparticles. The Au/THF also showed good recyclability and separation ability.

| S-EPMC8978662 | biostudies-literature

Aggregated mesoporous nanoparticles for high surface area light scattering layer TiO2 photoanodes in Dye-sensitized Solar Cells.

Project description:Hierarchically structured aggregates, consisting of TiO2 nanoparticles were produced via one-step solvothermal syntheses with a mixed solvent system containing both acetic acid and ethanol. Two of the resulting structures, one ~700?nm and the other ~300?nm in diameter, were found to be comprised of 8.5?nm and 10.5?nm anatase crystals, and possess specific surface areas of 138 and 106?m2?g-1 respectively. These particles were incorporated into Dye-sensitized Solar Cells (DSCs) as high surface area scattering layers, along with a layer of a transparent material. Solar-to-electric conversion efficiencies (PCE) of 9.1% and 8.2% were recorded using these aggregated particles as compared to those of commonly used large particles scattering layer 7.4%.

| S-EPMC5583389 | biostudies-literature