Dataset Information

Integrated Capacitive- and Resistive-Type Bimodal Relative Humidity Sensor Based on 5,10,15,20-Tetraphenylporphyrinatonickel(II) (TPPNi) and Zinc Oxide (ZnO) Nanocomposite.

ABSTRACT: The development of high-performance humidity sensors to cater for a plethora of applications, ranging from agriculture to intelligent medical monitoring systems, calls for the selection of a reliable and ultrasensitive sensing material. A simplistic device architecture, robust quantification of ambient relative humidity (% RH), and compatibility with the contemporary integrated circuit technology make a bimodal (capacitive and resistive) surface-type sensor to be a prominent choice for device fabrication. Herein, we have proposed and demonstrated a facile realization of a 5,10,15,20-tetraphenylporphyrinatonickel (II)-zinc oxide (TPPNi-ZnO) nanocomposite-based bimodal surface-type % RH sensor. The TPPNi macromolecule and ZnO nanoparticles have been synthesized by an eco-benign microwave-assisted technique and a thermal-budget chemical precipitation method, respectively. It is speculated from the morpohological study that specific surface area improvement, via the provision of ZnO nanoparticles on micro-pyramidal structures of TPPNi, may reinforce the sensing properties of the fabricated humidity sensor. The relative humidity sensing capacitive and resistive characteristics of the sensor have been monitored in 40-85% relative humidity (% RH) bandwidth. The fabricated sensor under the biasing conditions of 1 V of applied bias (V _rms) and 500 Hz AC test frequency exhibits a significantly higher sensitivity of 387.03 pF/% RH and 95.79 kΩ/% RH in bimodal operation. The average values of both the response and recovery times of the capacitive sensor have been estimated to be ∼30 s. It has also been debated why this high degree of sensitivity and considerable reduction in response/recovery time has been obtained. In addition, the intense and wide bandwidth spectral response of the TPPNi-ZnO nanocomposite indicates that it may also be utilized as a potential light-harvesting heterostructured nanohybrid in future studies.

SUBMITTER: Akram R

PROVIDER: S-EPMC9434763 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature

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Publications

Integrated Capacitive- and Resistive-Type Bimodal Relative Humidity Sensor Based on 5,10,15,20-Tetraphenylporphyrinatonickel(II) (TPPNi) and Zinc Oxide (ZnO) Nanocomposite.

Akram Rizwan R Saleem Muhammad M Farooq Zahid Z Yaseen Muhammad M Almohaimeed Ziyad M ZM Zafar Qayyum Q

ACS omega 20220821 34

The development of high-performance humidity sensors to cater for a plethora of applications, ranging from agriculture to intelligent medical monitoring systems, calls for the selection of a reliable and ultrasensitive sensing material. A simplistic device architecture, robust quantification of ambient relative humidity (% RH), and compatibility with the contemporary integrated circuit technology make a bimodal (capacitive and resistive) surface-type sensor to be a prominent choice for device fa ...[more]

PMID: 36061702

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Project description:In recent years, LC resonant sensors have gained widespread attention for their extensive applications in industries such as pharmaceutical storage and food transportation. A wireless passive sensor with a good sensing performance is proposed based on a GO/CNT-OH/Nafion nanocomposite. The sensor was fabricated via inkjet printing technology, and the surface morphology of the GO/CNT-OH/Nafion nanocomposite was characterized by SEM measurement. It is found that the MWCNTs support the GO layer and the hydrophobic chains of Nafion interact with the hydrophobic layer of GO, resulting in a larger cavity and hydrophilic surface of the entire material. This structure well reflects the fact that the mixing of MWCNTs and Nafion provides the entire material with a stronger water absorption. The experimental study shows that the proposed humidity sensor has a frequency variation of 103 kHz/%RH at low humidity (30-60% RH) and a sensitivity of 931 kHz/%RH at high humidity (60-95% RH), while the sensitivity value from 30-95% RH is 547 kHz/% RH. The response time and recovery time are 110 s and 115 s, respectively. In addition, the tests showed that the GO/CNT-OH/Nafion nanocomposite applied to the humidity sensor had a maximum humidity hysteresis of about 3% RH at 30-95% RH, the resonant frequency remained basically unchanged after 50 h of testing, and the whole sensor possessed a good stability. After conducting several repeated experiments, it was found that the resonant frequency error of the whole sensor was low and did not affect the overall sensing test, which proved the reproducible preparation of the sensor. Finally, the humidity-sensing mechanism of the proposed sensor was analyzed in this paper, and it was found that GO enhanced the hygroscopic properties of GO/CNT-OH/Nafion nanocomposite when it was supported by MWCNT-OH and included uniformly dispersed Nafion. Therefore, our proposed humidity sensor is suitable for humidity detection above 30% RH in both sealed and open environments.

Dataset Information

Integrated Capacitive- and Resistive-Type Bimodal Relative Humidity Sensor Based on 5,10,15,20-Tetraphenylporphyrinatonickel(II) (TPPNi) and Zinc Oxide (ZnO) Nanocomposite.

Publications

Integrated Capacitive- and Resistive-Type Bimodal Relative Humidity Sensor Based on 5,10,15,20-Tetraphenylporphyrinatonickel(II) (TPPNi) and Zinc Oxide (ZnO) Nanocomposite.

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