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2,4,6-Triphenyl-N-{(3E)-3-[(2,4,6-tri-phenyl-phen-yl)imino]-butan-2-yl-idene}aniline.


ABSTRACT: The title compound, C52H40N2, is disposed about a centre of inversion and the conformation about the imine bond [1.268 (3) Å] is E. The terminal benzene ring is approximately perpendicular to the central 1,4-di-aza-butadiene mean plane, forming a dihedral angle of 81.2 (3)°. Weak C-H⋯π and π-π [inter-centroid distance = 4.021 (5) Å] inter-actions help to consolidate the packing.

SUBMITTER: Zhang Y 

PROVIDER: S-EPMC9462208 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature

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2,4,6-Triphenyl-<i>N</i>-{(3<i>E</i>)-3-[(2,4,6-tri-phenyl-phen-yl)imino]-butan-2-yl-idene}aniline.

Zhang Yang Y   Yu Fan F   Li Pei P   Xu Mengli M   Xu Guoyong G   Li Weimin W   Wang Fuzhou F  

IUCrData 20200430 Pt 4


The title compound, C<sub>52</sub>H<sub>40</sub>N<sub>2</sub>, is disposed about a centre of inversion and the conformation about the imine bond [1.268 (3) Å] is <i>E</i>. The terminal benzene ring is approximately perpendicular to the central 1,4-di-aza-butadiene mean plane, forming a dihedral angle of 81.2 (3)°. Weak C-H⋯π and π-π [inter-centroid distance = 4.021 (5) Å] inter-actions help to consolidate the packing. ...[more]

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