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2,4,6-Trinitro-N-[4-(phenyl-diazen-yl)phen-yl]aniline.

ABSTRACT: The title compound, C(18)H(12)N(6)O(6), was prepared from the reaction of 4-(phenyl-diazen-yl)aniline (aniline yellow) with picryl-sulfonic acid. The dihedral angle formed by the two benzene rings of the diphenyl-diazenyl ring system is 6.55?(13)° and that formed by the rings of the picrate-aniline ring system is 48.76?(12)°. The mol-ecule contains an intra-molecular aniline-nitro N-H?O hydrogen bond.

SUBMITTER: Smith G

PROVIDER: S-EPMC3099790 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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2,4,6-Trinitro-N-[4-(phenyl-diazen-yl)phen-yl]aniline.

Smith Graham G Wermuth Urs D UD

Acta crystallographica. Section E, Structure reports online 20110323 Pt 4

The title compound, C(18)H(12)N(6)O(6), was prepared from the reaction of 4-(phenyl-diazen-yl)aniline (aniline yellow) with picryl-sulfonic acid. The dihedral angle formed by the two benzene rings of the diphenyl-diazenyl ring system is 6.55 (13)° and that formed by the rings of the picrate-aniline ring system is 48.76 (12)°. The mol-ecule contains an intra-molecular aniline-nitro N-H⋯O hydrogen bond. ...[more]

PMID: 21754214

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