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rac-12-Selena-13,14-di-aza-tri-cyclo-[9.3.0.0^2,4]tetra-deca-11,13-diene.

ABSTRACT: The centrosymmetric crystal structure of the title compound, C₁₁H₁₆N₂Se, is built up from alternating strands of (R,R)- and (S,S)-enanti-omers. These strands, which propagate along the c-axis direction, are composed of homochiral mol-ecules related to each other by twofold screw axes. The shape of the mol-ecule is an almost planar unit around the selena-diazole ring with a hexa-methyl-ene chain as an arched handle.

SUBMITTER: Detert H

PROVIDER: S-EPMC9462238 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature

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rac-12-Selena-13,14-di-aza-tri-cyclo-[9.3.0.02,4]tetra-deca-11,13-diene.

Detert Heiner H Schollmeyer Dieter D

IUCrData 20200811 Pt 8

The centrosymmetric crystal structure of the title compound, C11H16N2Se, is built up from alternating strands of (R,R)- and (S,S)-enanti-omers. These strands, which propagate along the c-axis direction, are composed of homochiral mol-ecules related to each other by twofold screw axes. The shape of the mol-ecule is an almost planar unit around the selena-diazole ring with a hexa-methyl-ene chain as an arched handle. ...[more]

PMID: 36338511

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