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(7R,8S,9S,12S)-1-Benz-yloxy-13,14-didehydro-12-hy-droxy-2,13-dimeth-oxy-N-methyl-morphinane.


ABSTRACT: In the title compound, C(26)H(31)NO(4), a sinomenine derivative, the angle between the two aromatic rings is 53.34?(4)°. The N-containing ring is in a chair conformation, while the other two non-planar rings are in a half-boat conformation. In the crystal, mol-ecules are linked by O-H?N inter-actions into a C(8) chain along [100].

SUBMITTER: Zheng XL 

PROVIDER: S-EPMC3201304 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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(7R,8S,9S,12S)-1-Benz-yloxy-13,14-didehydro-12-hy-droxy-2,13-dimeth-oxy-N-methyl-morphinane.

Zheng Xing-Liang XL   Jiang Ning-Fei NF   Luo Dan D   Gao Hong-Sheng HS   Ding Ai-Shun AS  

Acta crystallographica. Section E, Structure reports online 20110917 Pt 10


In the title compound, C(26)H(31)NO(4), a sinomenine derivative, the angle between the two aromatic rings is 53.34 (4)°. The N-containing ring is in a chair conformation, while the other two non-planar rings are in a half-boat conformation. In the crystal, mol-ecules are linked by O-H⋯N inter-actions into a C(8) chain along [100]. ...[more]

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