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(Chlorido/bromido)[(1,2,5,6-η)-cyclo-octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl-idene)rhodium(I).

ABSTRACT: A new triazole-based neutral Rh^I complex, [Rh(Cl_0.846Br_0.154)(C₆H₁₁N₃)(C₈H₁₂)], has been synthesized and structurally characterized. The Rh^I atom has a distorted square-planar coordination environment, formed by a bidentate cyclo-octa-1,5-diene (COD) ligand, an N-heterocyclic carbene and a halide ligand that shows substitutional disorder (Cl:Br = 0.846:0.154). No significant inter-molecular inter-actions other than van der Waals forces are found in the crystal structure. Diffraction data indicated a two-component inversion twin with a ratio of 0.95 (5):0.05 (5).

SUBMITTER: Rushlow J

PROVIDER: S-EPMC9462365 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature

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(Chlorido/bromido)[(1,2,5,6-η)-cyclo-octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl-idene)rhodium(I).

Rushlow Joshua J Astashkin Andrei V AV Albert Daniel R DR Rajaseelan Edward E

IUCrData 20210813 Pt 8

A new triazole-based neutral RhI complex, [Rh(Cl0.846Br0.154)(C6H11N3)(C8H12)], has been synthesized and structurally characterized. The RhI atom has a distorted square-planar coordination environment, formed by a bidentate cyclo-octa-1,5-diene (COD) ligand, an N-heterocyclic carbene and a halide ligand that shows substitutional disorder (Cl:Br = 0.846:0.154). No significant inter-molecular inter-a ...[more]

PMID: 36339455

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